Electronic Resource
Springer
Fresenius' Zeitschrift für analytische Chemie
161 (1958), S. 261-263
ISSN:
1618-2650
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Bismuthiol II reacts with trivalent arsenic and antimony to form complexes of compositions As(C8H5N2S3)3 and Sb(C8H5N2S3)3 respectively, while with stannous the reaction is not stoichiometric. The ions of arsenic and antimony can be estimated, from an acid solution, 0.1 N in hydrochloric or sulphuric acid, with the ammonium or the sodium chloride as the coagulant. The complexes have low melting points and they are soluble in organic solvents.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00463398
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