ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reversible 1,2 and 1,3 acyl migrations with retention of configuration are shown to occur in 2-hydroxy-3,4-diamino-pentane. In 2-hydroxy-3,4-bis(acetylamino)-pentane, where 1,2 and 1,3 migration of like acyl groupe compete, the former reaction was the only one observed. In 2-hydroxy-3-benzoylamino-4-acetylamino-pentane, where 1,2 benzoyl migration competes with 1,3 acetyl migration, the latter predominated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19550380706
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