ISSN:
0749-1581
Schlagwort(e):
(+)-Aromadendrene
;
(-)-Alloaromadendrene
;
(+)-Ledene
;
(-)-Dehydroaromadendrane
;
(-)-Globulol
;
(+)-Viridiflorol
;
2D Homonuclear and heteronuclear correlations
;
2D INADEQUATE
;
1H NMR
;
13C NMR
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The total assignment of the 1H and 13C NMR spectra of five aromadendrane derivatives, (+)-aromadendrene (1), (-)-alloaromadendrene (2), (+)-ledene (3), (-)-dehydroaromadendrane (4), (-)-globulol (5) and (+)-viridiflorol (6) has been performed. The 13C spectral assignment of globulol was achieved from DEPT and double quantum coherence measurements. The concerted application of 1H—1H homonuclear and 1H—13C heteronuclear two-dimensional chemical shift correlations provided other 13C and all 1H chemical shifts. Moreover, the 1H assignment for compounds 1—3 was reexamined from the high-field analysis of proton-proton coupling constants.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/mrc.1260290920
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