ISSN:
0887-624X
Keywords:
glycidyl vinyl ether
;
carbon dioxide
;
(2-oxo-1,3-dioxolan-4-yl) methyl vinyl ether
;
cationic polymerization
;
poly[(2-oxo-1,3-dioxolan-4-yl) methyl vinyl ether]
;
radical copolymerization of OVE
;
polymer reaction of P(OVE)
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(2-Oxo-1,3-dioxolan-4-yl) methyl vinyl ether (OVE) was synthesized with high yield by addition reaction of glycidyl vinyl ether with carbon dioxide using tetrabutylammonium bromide (TBAB) as a catalyst. OVE was also prepared by reaction with β-butyrolactone or sodium hydrogencarbonate in the presence of TBAB as the catalyst. Poly [(2-oxo-1,3-dioxolan-4-yl) methyl vinyl ether] [P(OVE)] was obtained with high yield by cationic polymerization of OVE catalyzed using boron trifluoride diethyl ether complex in dichloromethane. Polymers bearing pendant 5-membered cyclic carbonate groups were also prepared by radical copolymerization of OVE with some electron-accepting monomers. Furthermore, addition reaction of P(OVE) with alkyl amines yielded the corresponding polymer having pendant 2-hydroxyethyl carbamate residue with high conversions. © 1994 John Wiley & Sons, Inc.
Additional Material:
6 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1994.080320211
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