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  • Tobacco  (3)
  • (2-sulfoindole)-3-acetic acid  (2)
  • Chemical Engineering  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Phytochemistry 14 (1975), S. 1425-1428 
    ISSN: 0031-9422
    Keywords: (2-sulfoindole)-3-acetic acid ; Indoleacetic acid ; O"2, and HO.radicals. ; bisulfite oxidation ; dioxindole-3-acetic acid ; manganous ion
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Phytochemistry 14 (1975), S. 1425-1428 
    ISSN: 0031-9422
    Keywords: (2-sulfoindole)-3-acetic acid ; Indoleacetic acid ; O"2, and HO.radicals ; bisulfite oxidation ; dioxindole-3-acetic acid ; manganous ion
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 37 (1993), S. 593-598 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Amino acids ; Tobacco ; Pre-column derivatization ; Fluorescence detection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An HPLC method for the determination of primary amino acids in tobacco, based on precolumn derivatization with the fluorogenic reagent naphthalene-2,3-dicarboxaldehyde, is described. Sample preparation consists of a single step of extraction with waterethanol (1∶1, v/v) at ambient temperature (assisted by sonication), followed by filtration of an aliquot and addition of derivatization reagents. High performance liquid chromatographic separation of the derivatized amino acids is performed on a Novapak C-18 column using fluorescence detection with excitation and emission wavelengths set at 246 and 470 nm respectively. Extraction efficiency, matrix interferences and other important variables are studied. This method has been used to analyze different types of tobaccos including burley, bright and oriental with satisfactory results.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 47 (1998), S. 443-448 
    ISSN: 1612-1112
    Keywords: Solid phase microextraction ; Gas chromatography-nitrogen phosphorus detection ; Alkaloid analysis ; Tobacco
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The sampling approaches using solid phase microextraction (SPME) were evaluated for the analysis of tobacco alkaloids. Because of their low volatility and ionic nature, sampling alkaloids from the headspace of dry or wet tobacco samples often required more effort to improve extraction efficiency. Directly dipping the SPME fiber coated with polydimethylsiloxane film into the tobacco extract was proved to be a simple, effective tool for sampling alkaloids from tobacco. When combined with the practice of fast GC and nitrogen-phosphorus detection, nicotine and a group of selected minor alkaloids (i.e., nornicotines, myosmine, anabasine and anatabine) were separated with baseline resolution within 3 min. The detection limits for these alkaloids are below 0.1 μg mL−1. In addition, the carry-over problem frequently occurred in alkaloids analysis was eliminated. The influence of tobacco matrix and fiber aging on the partition of alkaloids, as well as the use of an internal standard to compensate these deviations, were also studied.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 33 (1992), S. 309-312 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Methoprene ; Tobacco
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A rapid sample preparation procedure combined with a short reversed-phase HPLC separation for the quantitation of methoprene residue in tobacco samples is described. A ground tobacco sample of 0.5 g is mixed with 3 mL of 2-propanol. The mixture is extracted for twelve minutes with the aid of sonication at an elevated temperature (45–55°C) and then filtered through a 0.45 μm disposable filter prior to injection on HPLC. No sample cleanup or solvent evaporation step is required. Chromatographic analysis is performed on a C-18 column and the analysis time is 12.5 minutes. The detection limit for methoprene in tobacco samples is one part per million (μg/g).
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 747-757 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pirt's model for microbial growth and product formation are reparameterized to obtain multiresponse models with common parameters. The dependent variables in the models are related through the available electron and carbon balance constraints. Covariance adjustment is used to reduce the growth model to a unit variate linear model with covariates. Therefore, standard multiple regression programs can be used to obtain combined point and interval estimates of true biomass energetic yield, true product yield and maintenance coefficient. This approach may yield “better” estimates than the maximum likelihood approach when an appropriately selected subset of covariates is used. Nonlinear estimation procedures are also considered; these procedures are efficient with few responses; however, as the number of responses per observation increase, they may require a lot of computing time. For illustration several data from the biochemical engineering literature are analyzed by the proposed methods.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 1206-1212 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A modified injection molding machine with a compression mechanism, and a mold with a movable wall and shut-off mechanism, were used to investigate the effects of processing parameters on the quality of injection-compression-molded polystyrene disks. The compression start-up time, compression force, melt temperature, and part thickness were selected processing parameters. The disk moldings were evaluated based on dimensional accuracy and birefringence. It is found that the compression start-up time affects packing time, and thus greatly affects the residual orientation. If the transition from packing to compression could start before peak cavity pressure, disks with low residual orientation could be obtained. High compression force improves part quality and reduces thickness. Since both compression-induced reduction and cooling-induced shrinkage are involved, the effects of temperature and thickness are not as straightforward as the trends in conventional injection molding.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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