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  • 1
    ISSN: 1573-1561
    Keywords: Fatty acid analysis ; double-bond location ; dimethyl disulfide adducts ; mass spectrometry ; pheromone ; Choristoneura fumiferana ; C. occidentalis ; C. pinus pinus ; Plusia chalcites ; Lepidoptera ; Tortricidae ; Noctuidae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract A rapid analytical procedure for the determination of the position of double bonds in mixtures of monounsaturated fatty acid methyl esters has been developed. The method is based on direct capillary GC-MS-EI analysis of dimethyl disulfide adducts. The procedure was applied to mixtures of monounsaturated fatty esters from pheromone gland extracts of three tortricids from theChoristoneura genus,C. fumiferana, C. occidentalis, andC. pinus pinus, and one noctuid from the Plusiinae subfamily,Plusia chalcites. A correlation was found between the known major pheromone components in the four species with the corresponding fatty acids. Some of the additional fatty acids may be precursors to as yet unidentified minor pheromone components, present in extremely small quantities, in these species.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1561
    Keywords: Zeiraphera canadensis ; spruce budmoth ; (E)-9-tetradecenyl acetate ; sex pheromone ; Lepidoptera ; Tortricidae ; Eucosminae ; trapping
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The analyses of virgin female sex pheromone gland extracts by gas chromatography (GC), GC-electroantennographic detection (GC-EAD) and GC-mass spectrometry (GC-MS) followed by field-trapping experiments, have identified (E)-9-tetradecenyl acetate (E9–14:Ac) as the primary sex pheromone component of the spruce budmoth,Zeiraphera canadensis. Dosages of 1.0–100.0 ⧎g ofE9–14:Ac impregnated in rubber septa provide effective trap baits.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-1561
    Keywords: Helicoverpa assulta ; Heliothis ; Lepidoptera ; Noctuidae ; hexadecanal ; (Z)-9-hexadecenal ; (Z)-11-hexadecenal ; hexadecyl acetate ; (Z)-9-hexadecenyl acetate ; (Z)-11-hexadecenyl acetate ; hexadecan-1-ol ; (Z)-9-hexadecen-1-ol ; (Z)-11-hexadecen-1-ol ; sex pheromone
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Analysis of ovipositor washings from virgin femaleHelicoverpa assulta (Guenée) (Lepidoptere: Noctuidae) from Korea by gas chromatography (GC) linked to electroantennography and GC linked to mass spectrometry resulted in the identification of nine compounds, hexadecanal, (Z)-9-hexadecenal, (Z)-11-hexadecenal, hexadecyl acetate, (Z)-9-hexadecenyl acetate, (Z)-11-hexadecenyl acetate, hexadecan-l-ol, (Z)-9-hexadecen-l-ol, and (Z)-11-hexadecen-1-ol. However, ovipositor washings from females from Thailand contained mainly the 16-carbon aldehydes with very small amounts of (Z)-9-hexadecenyl acetate. Field tests conducted in Korea, China, and Thailand indicated that a binary blend of (Z)-9-hexadecenal and (Z)-11-hexadecenal was sufficient for attraction, although the most attractive ratio of compounds varied with location. In Korea a 20∶1 blend of compounds was the most attractive, while in Thailand a 7.5∶1 blend was most attractive. In China both blends of hexadecenal isomers were equally attractive. Addition of the hexadecenyl acetates to the 20∶1 blend of hexadecenals in the ratio of 1∶3.3 increased the trap catch of maleH. assulta compared to lures containing the aldehydes alone in Korea but reduced trap catch in China. Addition of the hexadecenyl acetates to the 7.5∶1 blend of hexadecenals had no significant effect on trap catch in Thailand or China compared to the aldehydes alone. The addition of the 16-carbon alcohols to the aldehydes had a significantly inhibitory effect in all three countries, suggesting they are not pheromone components. Taken together these results indicate thatH. assulta is polymorphic with at least two populations responding to different sex pheromones.
    Type of Medium: Electronic Resource
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