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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 26 (1993), S. 92-94 
    ISSN: 1434-6079
    Keywords: 36.40.+d ; 03.65.Sq ; 33.80.Eh ; 35.20.Vf
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Neutral aluminum clusters have been produced by laser vaporization technique, ionized by a low-power near-threshold laser light and detected using standard TOF spectrometric methods. Ionization potentials have been deduced in the low size range. In the large size range 250〈N〈1400 the patterns of the mass spectra exhibit a regular and continuous oscillation, originating from size-dependent ionization threshold effects. The period, constant on a Ne 1/3 scale (Ne=3N is the number of valence electrons), is approximately two times shorter than the one observed in alkali experiments. This feature is analyzed in terms of shell structure.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-6079
    Keywords: PACS: 36.40.-Qv Stability and fragmentation of clusters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. Silicon–carbon binary clusters with various mean compositions are generated in a laser vaporization source from targets processed as mixtures of graphite and silicon powders. Their size distribution is first analyzed by time-of-flight mass spectroscopy, which shows the stability of carbon fullerenes doped with silicon atoms in substitutional sites. Further investigations on the level of silicon doping are carried out by means of the laser-induced fragmentation of selected sizes. The photoproduct size distributions give evidence for at least nine silicon atoms substituted into still stable fullerene networks. The synthesis of heterofullerenes is mainly assisted by the nucleation mechanisms from Si-C mixed atomic vapors. Just as in the case of externally doped fullerene precursors, the laser-induced annealing of stoichiometric silicon-carbide clusters appears as an alternative route to produce heterofullerenes in the gas phase.
    Type of Medium: Electronic Resource
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