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  • reactivity  (2)
  • 05.10.Ln  (1)
  • 25.70.Gh  (1)
  • 61.72.Ji  (1)
  • 1
    ISSN: 1432-0630
    Keywords: 61.72.Cc ; 61.72.Ji ; 73.61.Cw
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Vacancy-related defects introduced into n-Si during annealing or aluminium diffusion at high temperature (1000–1250°C) have been studied. Different ambients (argon, nitrogen, vacuum and chlorine-containing atmosphere) were used to create a vacancy supersaturation during heat treatments. Three deep-level centers whose formation is governed by the presence of vacancies have been identified. They were characterized by the following temperature dependences of the thermal emission rate:e3 = 7.92 × 107 T 2 × exp(− 0.455/kT),e 5 = 2.64 × 106 T 2 × exp( − 0.266/kT),e 7 = 7.26 × 106 T 2 × exp (− 0.192/kT). The influence of different factors, such as heat-treatment conditions, concentration of oxygen and doping level in initial crystals, on center formation was studied. An asymmetric diffuseγ-ray scattering was observed near the surface of a crystal irradiated by thermal neutrons and annealed in a chlorine-containing atmosphere. This scattering is related to the formation of structural defects of the vacancy type. In the same region of the crystal, the concentration of the E7 center was one order of magnitude higher than that of other deep-level centers. Comparison of theγ-ray diffraction and deeplevel transient spectroscopy (DLTS) data suggests that the formation of the center occurs under the conditions of Si supersaturation with vacancies.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1090-6487
    Keywords: 75.10.−b ; 64.60.Ak ; 64.60.Cn ; 05.10.Ln
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We study the critical behavior of frustrated systems by means of the Padé-Borel resummed three-loop renormalization group expansions and numerical Monte Carlo simulations. Amazingly, for six-component spins, where the transition is second-order, both approaches disagree. This unusual situation is analyzed both from the point of view of the convergence of the resummed series and from the possible relevance of nonperturbative effects.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 41 (1992), S. 1750-1755 
    ISSN: 1573-9171
    Keywords: vinyl monomers ; radical addition ; reactivity ; correlation schemes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The concept of the apparent electronegativity of a reaction site has been introduced. This has been used to develop a new scheme for calculating the relative rate constants of addition of radicals with different structures to vinyl monomers. The parameters of the scheme are given for 40 reagents. The results of a comparison of calculated and literature rate constants of addition are presented.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 41 (1992), S. 2147-2151 
    ISSN: 1573-9171
    Keywords: vinyl monomers ; radical oxidation ; inhibitors ; phenols ; reactivity ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Rate constants were measured for the addition of the 2,4,6-tri(tert-butyl)phenoxyl radical (logk 10, [liter/(mole · sec)]) to the double bond of styrene (9.73 − 4621/T), methyl methacrylate (10.1 − 4972.7/T) and butylacrylate (7.68 − 4313.9/T); and for addition of the 2,4,6-tribromophenoxyl radical to styrene (k 10=0.5;T=323 K). A simulation based on these constants for the inhibited oxidation of styrene under conditions similar to those of monomer storage demonstrated the need to take account of this reaction when analyzing kinetic schemes describing the inhibited oxidation process.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1434-601X
    Keywords: 25.70.Gh ; 25.70.Lm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Inclusive neutron multiplicity distributions were measured by means of 4π liquid-scintillator detectors for Ar and Kr-induced reactions at 44 MeV/nucleon and 32 MeV/nucleon, respectively. For all the systems studied, the observed distributions exhibit a bump structure at large multiplicity, corresponding to highly dissipative collisions. For Ar-induced reactions, the excitation energies necessary to explain the most probable neutron multiplicity associated with these dissipative collisions are estimated, the correspondence between excitation energy and neutron multiplicity being calculated in the framework of the statistical model. The so-obtained values of excitation energies, which are systematically lower than those predicted using the massive-transfer picture, are discussed.
    Type of Medium: Electronic Resource
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