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  • 07.65  (1)
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    ISSN: 1432-0649
    Keywords: 07.65 ; 33.00 ; 42.60 ; 42.65 ; 42.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Spectroscopic detection of the methane in natural air using an 800 nm diode laser and a diode-pumped 1064 nm Nd:YAG laser to produce tunable light near 3.2 µm is reported. The lasers were pump sources for ring-cavity-enhanced tunable difference-frequency mixing in AgGaS2. IR frequency tuning between 3076 and 3183 cm−1 was performed by crystal rotation and tuning of the extended-cavity diode laser. Feedback stabilization of the IR power reduced intensity noise below the detector noise level. Direct absorption and wavelength-modulation (2f) spectroscopy of the methane in natural air at 10.7 kPa (80 torr) were performed in a 1 m single-pass cell with 1 µW probe power. Methane has also been detected using a 3.2 µm confocal build-up cavity in conjunction with an intracavity absorption cell. The best methane detection limit observed was 12 ppb m (Hz.)−1/2.
    Type of Medium: Electronic Resource
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