ISSN:
0170-2041
Keywords:
Ketene acetals, 2-(trimethylsilyl)-
;
Trialkylsilyl trifluoromethanesulfonates
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reactions of Trialkylsilyl Trifluoromethanesulfonates, IX. - Electrophilic Silylation of Electron-Rich AlkenesKetene O,O-, O,S-, and O,N-acetals 1, 7, and 9 are converted into the C-silylated derivatives 4, 8, and 11, respectively, by reaction with trimethylsilyl triflate (2a)/tertiary amine or sodium hydride. The ambident character of the ketene O,O-acetals 1 in the silylation with 2a is studied.
Additional Material:
9 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.1990199001140
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