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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 97 (1987), S. 3-13 
    ISSN: 1573-5036
    Keywords: AN value ; Isotope dilution ; 15N ; N balance ; N2 fixation ; Soil nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Accurate estimates of N2 fixation by legumes are requisite to determine their net contribution of fixed N2 to the soil N pool. However, estimates of N2 fixation derived with the traditional15N methods of isotope dilution and AN value are costly. Field experiments utilizing15N-enriched (NH4)2SO4 were conducted to evaluate a modified difference method for determining N2 fixation by fababean, lentil, Alaska pea, Austrian winter pea, blue lupin and chickpea, and to quantify their net contribution of fixed N2 to the soil N pool. Spring wheat and non-nodulated chickpea, each fertilized with two N rates, were utilized as non-fixing controls. Estimates of N2 fixation based on the two control crops were similar. Increasing the N rate to the controls reduced AN values 32, 18 and 43% respectively in 1981, 1982 and 1983 resulting in greater N2 fixation estimates. Mean seasonal N2 fixation by fababean, lentil and Austrian winter pea was near 80 kg N ha−1, pea and blue lupin near 60 kg N ha−1, and chickpea less than 10 kg N ha−1. The net effects of the legume crops on the soil N pool ranged from a 70 kg N ha−1 input by lentil in 1982, to a removal of 48 kg N ha−1 by chickpea in 1983. Estimates of N2 fixation obtained by the proposed modified difference method approximate those derived by the isotope dilution technique, are determined with less cost, and are more reliable than the total plant N procedure.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 21 (1983), S. 573-581 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: 13C NMR spectra of propylene-1-butene copolymers have been studied at 90.55 MHz. At this high field, many lines previously not resolvable were found to be sensitive to comonomer sequence distribution; these microstructures have been fully assigned. Each NMR spectrum was analyzed by a reaction probability model. Information available includes polymer composition, comonomer sequence distribution, and Markovian reaction probabilities. The use of this model reduces errors in the determination of sequence distribution and furthermore enables the product r1r2 of the reactivity ratios to be determined for the copolymer/catalyst system.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 461-470 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Carbon-13 NMR spin-lattice relaxation times T1 of poly(N-vinyl pyrrolidone) (PVP) and PVP-iodine have been studied in several solvents and at different temperatures. Three kinds of motion can be identified from the T1 data: segmental motion, ring rotation, and ring puckering. The effective correlation time for segmental motion is calculated to be 1 × 10-9s, in good agreement with published proton NMR data. Another solvent, 1,1,2,2-tetrachloroethane, behaves like D2O, the segmental correlation time being 3 × 10-9s. In benzene, however, the linewidths are very broad and tend to narrow with increasing temperature, but the T1s are not very different from those of PVP in D2O. The results suggest association of pyrrolidone rings in benzene that reduces chain dimensions and also restricts chain mobility. As for PVP-iodine in water, again broad resonances are observed which sharpen considerably at higher temperatures. The result agrees with previous suggestions of specific interactions between the pyrrolidone group and iodine.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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