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  • Organic Chemistry  (7)
  • General Chemistry  (2)
  • expert systems  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Planning systems and artificial intelligence (1988)
    Springer
    Annals of operations research 16 (1988), S. 1-12 
    Details
    ISSN: 1572-9338
    Keywords: Planning systems ; expert systems ; knowledge representation ; inspection plans ; construction plans
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Notes: Abstract Traditional O.R. systems are compared with problem solving in Artificial Intelligence via Expert Systems. The discussion centers on explicit knowledge representation. The general aspects are illustrated by two planning systems: · LESP 2: A learning system for inspection plan generation · IDA: A system for finding functions and solutions in construction
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02283732
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  • 2
    Electronic Resource
    Electronic Resource
    Zum Reaktionsverhalten von Carbonsäureamiden gegenüber Schwefelkohlenstoff und Isothiocyanaten (1982)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 324 (1982), S. 625-630 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction Behaviour of Amides with Carbondisulphide and IsothiocyanatesReactions of substituted arylamides, hetarylamides and furylacrylicamide 1 with carbon disulphide present a possibility to synthesize imino-dithiocarbonic-S,S′-diester 5. The mechanism of the reaction and the reaction conditions are investigated. Quantum chemical investigations by simple HMO-method in connection with the experimental results describe the reaction in dependence upon the influence of substituent in 2- and 4-position to the phenylring. Further more is described the reaction of amide with isothiocyanates to thiourea 6 and isothiourea 7.The structures of the final products are determined by analytical dates.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19823240418
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    1H- und 13C-NMR-Untersuchungen an N-Acyl-imino-dithio-kohlensäure-S,S-dimethylestern (1983)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 1011-1015 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1H- and 13C-N.M.R. Investigations of N-Acyl-imino-dithiocarbonic-S,S-dimethylester
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19833250618
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  • 4
    Electronic Resource
    Electronic Resource
    Reaktionen von Aroyl(Hetaroyl)iminodithiokohlesäureestern mit Carbanionen CH-acider Verbindungen (1983)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 675-679 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactions of Dimethyl N-Aroyl(Hetaroyl)carbimidodithioates with Carbanions CH-acidic CompoundsReactions of dimethyl N-aroyl(hetaroyl)carbimidodithioates 1 with carbanions 2 present new possibilities to synthesize 3-acyl-amino-3-methylthio-2-subst.-acrylnitriles 3 by monosubstitution of methylthiogroup.The reaction of 1 with 2-alkyl-benzothiazolium salts 4 yield deeply coloured N-acyl-(2,3-dihydrobenzothiazole-2-yliden) thioacetimido acid-methylates 5 of the 2-subst.-benzothiazoliumperchlorates 6. The structures of the final products are determined by i.r.-, 1H.-n.m.r.- and u.v.-spectra.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19833250417
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  • 5
    Electronic Resource
    Electronic Resource
    Synthese und Reaktionsverhalten von N-(3-Chlorbenzo[b]-thiophen-2-carbonyl)imino-Dithiokohlensäure-Derivaten (1984)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 326 (1984), S. 633-637 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis and Reaction Behaviour of N-(3-Chlorobenzo[b]thiophene-2-carbonyl)-imino-dithiocarbonic Derivatives3-Chlorobenzo[b]thiophene-2-carbonyl-chloride 1 was treated with potassium rhodanide to afford the appropriate acyl isothiocyanate 3, which adds nucleophilic agents as amines and thioles in good yields.Addition of methanethiole and subsequent alkylation of the dithiocarbamate 7 gives S, S-dimethylimino-dithiocarbonate 8. 3-Chlorobenzo[b]thiophene-2-carboxamide 2 reacts with carbon disulphide and phenyl isothiocyanate by chlorine substitution and cyclisation to benzo[b]thieno[2, 3-e]thiazines 9, 10 or 11. The structure of the final products were determined by analytical and spectroscopical dates.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19843260416
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  • 6
    Electronic Resource
    Electronic Resource
    A sophisticated expert system for the diagnosis of a CNC machining center (1988)
    Springer
    Mathematical methods of operations research 32 (1988), S. 251-269 
    Details
    ISSN: 1432-5217
    Keywords: expert systems ; diagnosis ; deep models ; knowledge acquisition ; learning ; temporal representation ; mechanical engineering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Description / Table of Contents: Zusammenfassung Im gleichen Maße, wie diagnostische Expertensysteme in immer umfangreichere und komplexere Aufgabenstellungen vordringen, zeigt sich, daß ausschließlich regelbasierte, assoziative Ansätze keine angemessene Lösung mehr darstellen. Ein typisches Beispiel für eine solche Situation ist die Diagnose von CNC-Bearbeitungszentren, deren komplexe innere Struktur und die spezifische Vorgehensweise des Experten explizit in der Wissensbasis repräsentiert werden müssen. In diesem Artikel beschreiben wir drei Richtungen, in denen die“konventionelle” Expertensystemarchitektur erweitert werden kann, um den gestiegenen Anforderungen zu entsprechen. Unser System stützt sich auf ein Struktur- und Funktionsmodell des Bearbeitungszentrums, das das in Regelform gespeicherte Wissen ergänzt. Die Verwendung des Modells stellt neuartige Anforderungen an die Wissensakquisition, die durch eine enge Verzahnung mit dem Lernmechanismus des Expertensystems unterstützt wird. Schließlich gehen wir auf die zeitlichen Aspekte der Diagnosesituation ein, die eine spezielle Behandlung der dynamischen Maschinenprozesse und der sich darin entwickelnden Fehler erfordern.
    Notes: Abstract As the domains of diagnostic expert systems become larger and more complex, purely associative approaches are no longer adequate solutions. A good example for such a situation is the diagnosis of a CNC machining center where the diagnostic process has a rich inner structure that has to be reflected in the system. In this article we describe three ways of extending the conventional expert system architecture. Firstly, our system uses a structural model of the machining center in addition to production rules. Secondly, we pay special attention to knowledge acquisition which is intimately related to the learning process. Finally, several temporal aspects of the diagnostic situation are addressed explicitly.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01928926
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    Paper (German National Licenses)
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  • 7
    Electronic Resource
    Electronic Resource
    Verbesserte calorimetrische Heizwertbestimmung flüssiger Brennstoffe in Platingefäßchen (1938)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 51 (1938), S. 146-147 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19380511004
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  • 8
    Electronic Resource
    Electronic Resource
    Verbesserungsvorschläge für die Elementarbestimmung von flüssigen Treibstoffen nach der Halbmikromethode (1938)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 51 (1938), S. 147-148 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19380511005
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  • 9
    Electronic Resource
    Electronic Resource
    Über aromatische Derivate der Orthoschwefligsäure (1918)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 416 (1918), S. 291-304 
    Details
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.19184160213
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  • 10
    Electronic Resource
    Electronic Resource
    Reaktionen mit N-Acylimino-dithiokohlensäurediestern (1980)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 322 (1980), S. 55-68 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactions with N-Acylimino-dithiocarbonic-acid-diesters.Reactions of N-acylimino-dithiocarbonic-acid-S,S-diesters 1 with nucleophilic com-pounds present new possibilities to synthesize heterocycles. With amines 1a reacts by mono- and disubstitution, respectively, of methylthio-groups to isothioureas 2 and guanidines 3, with 1,2-bi-nucleophilic arenes to benzoheterocycles 4, with aliphatic diamines to imidazolidines 5, pyrimidines 6, diazepines 7 and the hexamethylene-diamine-derivatives 8. 1a reacts also with hydrazines to 1,2,4-triazoles 9 and with hydrazides to the thiosemicarbazones 10 or 1,3,4-oxadiazoles 11. Heterocyclisations of 1 with guanidines, thiourea, salts of thiourea and amidines give the 1,3,5-triazines 12, 14, 15 and 16. N-benzoyl-dithiocarbonic-acid-methylester -amid reacts with CH-acidic compounds to thiazoles 17. The structures of the final products are determined by i.r.-, 1H-n.m.r.-, u.v.- and mass-spectras.
    Additional Material: 9 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19803220109
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