Bibliothek

X
feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • Physics  (6)
  • 19F solid-state NMR spectroscopy  (1)
  • cellular automata  (1)
  • 1
    Digitale Medien
    Digitale Medien
    One-Dimensional Lattice Dynamics of the Diffusion-Limited Reaction A+A→A+S: Transient Behavior (2000)
    Springer
    Journal of statistical physics 99 (2000), S. 1397-1407 
    Details
    ISSN: 1572-9613
    Schlagwort(e): nonequilibrium reaction–diffusion systems ; cellular automata ; differential-difference equations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We use a Boolean cellular automaton model to describe the diffusion-limited dynamics of the irreversible reaction A+A→A+S on a 1D lattice. We derive a set of equations for the dynamics of the empty interval probabilities from which explicit expressions for the particle concentration and the two-point correlation can be obtained. It is shown that the long-time dynamics is in agreement with the off-lattice solution. The early-time behavior, however, predicts a slower decay of the concentration.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1018649108442
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 2
    Digitale Medien
    Digitale Medien
    High-resolution solid-state 19F-NMR spectroscopy of the sorption and diffusion of fluorine-containing aromatic molecules in polymeric media (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 859-863 
    Details
    ISSN: 0887-624X
    Schlagwort(e): 19F solid-state NMR spectroscopy ; dual-mode sorption ; diffusion coefficients ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: High-resolution 19F solid-state NMR spectroscopy was employed to study the sorption properties of hexafluorobenzene (HFB) and 3,5-bis (trifluoromethyl) aniline (TFMA) in polystyrene (PS) and butyl rubber (BR). The NMR spectra indicate that the penetrants undergo dual-mode sorption in the glassy polymer (PS), but are highly mobile in the rubbery polymer (BR). In addition, the NMR method was utilized in the experimental determination of diffusion coefficients for the HFB/PS, TFMA/PS, and HFB/BR systems through desorption studies. The diffusion results for the TFMA/PS case agree very well with those previously obtained via resonance nuclear reaction analysis. © 1993 John Wiley & Sons, Inc.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pola.1993.080310403
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 3
    Digitale Medien
    Digitale Medien
    Relaxation of chemical potential and a generalized diffusion equation (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 675-682 
    Details
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The effect of slow structural relaxation in a solvent of high viscosity on the chemical potential driving the diffusion of penetrant molecules is described by a generalized diffusion equation with a memory term. The linearized version of this equation is solved for some special cases, and the correlation function of concentration fluctuations in thermodynamic equilibrium is calculated. As a result of the memory term, for very slow relaxation two different stages of the diffusion process can be distinguished.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1985.180230405
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 4
    Digitale Medien
    Digitale Medien
    Two-component interpenetrating polymer networks (IPNs) from polyurethanes and epoxies. II. Effect of different charge groups in polyurethanes and epoxies on properties and morphologies of two-component IPNsFor Part I, see J. Polym. Sci. Polym. Chem. Ed., 22, 1839-1850 (1984). (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1851-1863 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Two-component interpenetrating polymer networks (IPNs) that contained charge groups in the backbones of the polyurethane and epoxy networks were studied. IPNs that contained opposite charge groups, similar charge groups, no charge groups, and corresponding pseudo-IPNs were prepared. A comparison of mechanical properties, water-resistance data, mechanical spectra, and electron microscopy showed that improved properties and morphologies resulted in IPNs that contained opposite charge groups. Presumably, interactions between the opposite charge groups in the constituent networks resulted in a forced compatibility between the two polymers which decreased the degree of phase separation.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1984.170220807
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 5
    Digitale Medien
    Digitale Medien
    Three-component interpenetrating polymer networks (IPN's) from polyurethanes, epoxies, and poly(methacrylates) (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2667-2683 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Three-component IPN systems made from polyurethanes, epoxies, and poly(methacrylates) containing charge groups in the backbones of the constituent networks have been prepared. Specific attractive forces that occurred among the various networks helped to compatibilize them and aided in the formation of true homogeneous topologically interpenetrating polymer networks. These three-component polymer alloys, including full-IPN's, pseudo-IPN's, and graft-IPN's, were characterized by means of mechanical spectroscopy, electron microscopy, and stress-strain properties. In addition, some adhesion studies were carried out (lap shear strength and peel strength). A comparison of the different types of three-component polymer alloys showed that better properties were generally exhibited by the graft-IPN's and full-IPN's containing opposite charge groups.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1984.170221031
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 6
    Digitale Medien
    Digitale Medien
    Synthesis and characterization of crosslinked polydiacetylene and its two-component interpenetrating polymer networks (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 1163-1173 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis of crosslinked polydiacetylenes and its two-component interpenetrating polymer networks (IPNs) was carried out utilizing its polar and flexible substituent groups. Polydiacetylenes were crosslinked by the formation of allophanate linkages utilizing urethane groups in the substituent groups of the polydiacetylenes. Elemental analysis, DSC, TMA, solvent resistance, and IR spectra are presented as evidence for the formation of crosslinked polydiacetylenes. IPNs of polydiacetylenes and an epoxy resin (diglycidyl ether of bisphenol A) were synthesized by using simultaneous and sequential methods of synthesis. A study of phase morphology of the simultaneous and sequential IPNs was carried out using electron microscopy, TMA, and DSC.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1985.170230420
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 7
    Digitale Medien
    Digitale Medien
    Two-component interpenetrating polymer networks (IPNs) from polyurethanes and epoxies. I. Studies on full IPN, pseudo-IPN, and graft polymer alloys of polyurethanes and epoxies (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1839-1850 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: In this article we review the synthesis and morphology and the physical and mechanical properties of two-component interpenetrating polymer networks (IPNs) from polyurethane and epoxy polymers; the corresponding pseudo-IPNs and grafted IPNs are also discussed. A comparison was made of full IPNs, pseudo-IPNs, grafted IPNs, and related homopolymers by examining their mechanical properties, mechanical spectra, and electron microscopy on an investigation of the effects of interpenetration or permanent entanglement in the IPN and related systems. This interpenetration has resulted in improved compatibility between the two polymer systems and has caused a decrease in the degree of phase separation. An observed shift in the dynamic glass transition temperatures (Tgs) of the two components which yielded a single IPN Tg further substantiates our results.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1984.170220806
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 8
    Digitale Medien
    Digitale Medien
    Model reactions for crosslinking polydiacetylene materials (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 1175-1192 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A series of reactions are presented which allowed us to crosslink polydiacetylenes containing carbamate groups in the side chain without attacking the triple bond. These reactions involved syntheses of carbamates and allophanates from butyl alcohol and phenyl isocyanate with metal and tertiary amine catalysts using a model compound, 2,4,7,9-tetramethyl-5-decyn-4,7-diol. Elemental analysis, IR and UV spectroscopy, and high performance liquid chromatography (HPLC) were used as analytical tools. Metal catalysts were found to favor the formation of allophanates in higher yields and purity as compared to tertiary amine catalysts.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1985.170230421
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...