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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 66 (1992), S. 727-754 
    ISSN: 1572-9613
    Schlagwort(e): Fully developed chaos ; local Lyapunov exponent ; thermodynamics ; exact solutions ; first-order phase transitions ; entropy ; coexisting states
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Fluctuations in the divergence of nearby orbits are studied at a crisis point of chaos. A statistical-thermodynamic method for the description of the fluctuations is developed by using symbolic dynamics, which can explicitly write a relation between a fluctuation and reference orbit. The thermodynamics (the free energy and entropy) is exactly analyzed on a nonhyperbolic attractor of maps conjugate to the map:u→u/a for 0〈/u〈a andu→(1−u)/(1−a) fora⩽u⩽1. Te free energy has discontinuities in its slope. The entropy is directly calculated from the partition function. Then, it becomes clear that the collision of a chaotic attractor with a particular fixed point yields a singular local structure in the distribution of fluctuations. The existence of first-order phase transitions depends on the asymmetry of a map. It is shown that each of the coexisting states at the phase transition points is realized with the same probability in the thermodynamic limit.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 71 (1993), S. 981-1002 
    ISSN: 1572-9613
    Schlagwort(e): Fluctuations ; 1D Ising model ; exact results ; distribution function ; zero-temperature limit ; first-order phase transition ; helix-coil transition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Fluctuation of the average spin for one-dimensional Ising spins with nearest neighbor interactions are studied. The distribution function for the average spin is calculated for a finite volume, finite temperature, and finite magnetic field. As the volume increases and the temperature diminishes at zero magnetic field, there are two limits in which the probability distribution shows quite different behaviors: in the thermodynamic limit as the volume goes to infinity for finite temperature, small deviations of the fluctuations are described by a Gaussian distribution, and in the limit as the temperature vanishes for a finite volume, the ground states are realized with probability one. The crossover between these limits is analyzed via a ratio of the correlation length to the volume. The helix-coil transition in a polypeptide is discussed as an application.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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