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  • polymer solutions  (2)
  • 2,2,6,6-tetramethylpiperidinyl methacrylate  (1)
  • 1
    Electronic Resource
    Electronic Resource
    A new nonrandom lattice fluid model and its simplification by two-liquid theory for phase equilibria of complex mixtures (1995)
    Springer
    International journal of thermophysics 16 (1995), S. 723-731 
    Details
    ISSN: 1572-9567
    Keywords: complex mixtures ; equation of state ; multiphase equilibria ; nonrandom lattice theory ; polymer solutions ; supercritical fluids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new riogorous equation of state (EOS) and its simplified version have been proposed by the present authors based on the full Guggenheim combinatorics ] of the nonrandom lattice hole theory. The simplified EOS. with the introduction of the concept of local composition, becomes similar to the density-dependent UNIQUAC model. However, im the present approach we have a volumetric EOS instead of the excess Gibbs function. Both EOSs were tested for their applicability in correlating the phase equilibria behavior of pure components and complex mixtures. Comparison of both models with experiment includes such systems as nonpolar nonpolar, nonpolar polar, and polar polar hydrocarbons, supercritical systems, and polymer solutions. With two parameters for each pure component and one binary interaction energy parameter, results obtained to date demonstrate that both formulations are quantitatively applicable to complex systems oer a wide range of temperatures, pressures, and concentrations.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01438857
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Predicting Specific Volumes of Pure Polymers and VLE of Polymer Solutions by Group-Contribution Lattice Theory (1998)
    Springer
    International journal of thermophysics 19 (1998), S. 707-717 
    Details
    ISSN: 1572-9567
    Keywords: lattice-hole theory ; polymer solutions ; specific volume ; vapor–liquid equilibria
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A generalized group-contribution (GC) scheme with an equation of state (EOS) presented previously by the present authors was extended to the prediction of specific volumes of pure polymers and vapor–liquid equilibria of polymer solutions. The GC-EOS requires only two parameters, representing group size and interaction between groups. A unique feature of the approach is that a single set of group information can be applied to predict both the configurational properties of pure polymers and mixtures in general. The approach was illustratively applied to the prediction of the density of pure polymers, vapor pressures of organic solvents, and phase equilibria of their polymer solutions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022618301397
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Polymerization behavior of 2,2,6,6-tetramethylpiperidinyl methacrylate: A monomer carrying a hindered amine group (1992)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 983-988 
    Details
    ISSN: 0887-624X
    Keywords: copolymerization ; 2,2,6,6-tetramethylpiperidinyl methacrylate ; HALS ; copolymer structure ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copolymers of 2,2,6,6-tetramethylpiperidinyl methacrylate (TPMA) with styrene (S) and with methyl methacrylate (MMA) were synthesized using AIBN as initiator. S-TPMA copolymers from feed ranging from 0.10-0.80 mole fractions TPMA and MMA-TPMA copolymers from feed of 0.04-0.85 mole fractions TPMA were used in the determination of monomer reactivity ratios r1, r2. Four different methods were employed in the calculations of r1 and r2 and all calculated results were in good agreement with each other. The structure of S-TPMA copolymers was inferred to be of an alternating nature while that of MMA-TPMA copolymers was random. Both copolymers are potential hindered amine light stabilizers (HALS) and are expected to be less extractable from, and more compatible with, polystyrene and poly(methyl methacrylate) base polymers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1992.080300604
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    Paper (German National Licenses)
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