ISSN:
1434-4475
Keywords:
5,6,7,8-Tetrahydrobenzo[f]indane and derivatives
;
Mono- and bisanellation
;
2,2′-Spirobiindane
;
1H-nmr and mass spectra
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The title compounds26 and32 were prepared by systematic mono- and bisanellation of sixmembered rings to the positions 5,6 and 5′,6′, resp. of 2,2′-spirobiindane.S E acylation and subsequent transformations of the acylgroups afforded many derivatives with substituents in positions 4 and 4′ of the parent compounds which were required for testing semiempirical values of chirality functions. 5,6,7,8-Tetrahydrobenz[f]indane (9) and several of its 4-substituted derivatives were prepared as models for the anellation and substitution reactions. Tentative preferred conformations of the 4-acylgroups could be deduced from1H-nmr spectra.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00798792
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