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  • Physics  (3)
  • 2,3-bisphosphoglycerate  (1)
  • 73C10  (1)
  • 1
    ISSN: 1432-0428
    Keywords: Haemoglobin A1c ; Type 1 diabetes ; oxygen dissociation curve ; 2,3-bisphosphoglycerate ; p50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Increased erythrocyte 2,3-bisphosphoglycerate concentrations are associated with increased haemoglobin glycosylation in patients with Type 1 diabetes mellitus who have no cause or symptoms of hypoxic stress. This change in 2,3-bisphosphoglycerate metabolism is additional to its response to changes in circulating haemoglobin concentration. Statistical analysis of data showed that erythrocyte 2,3-bisphosphoglycerate concentration did not correlate with the absolute concentration of circulating haemoglobin A1c, but with the proportion of haemoglobin glycosylated. This finding is consistent with the hypothesis that it is changes in the position of the erythrocyte oxygen dissociation curve which modulate the increase in 2,3-bisphosphoglycerate synthesis upon haemoglobin A1c formation.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of elasticity 30 (1993), S. 1-54 
    ISSN: 1573-2681
    Keywords: elastic beam theory ; subcentre invariant manifolds ; dynamical systems ; 73C02 ; 73C10 ; 35A35 ; 58G40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The subcentre invariant manifold of elasticity in a thin rod may be used to give a rigorous and appealing approach to deriving one-dimensional beam theories. Here I investigate the analytically simple case of the deformations of a perfectly uniform circular rod. Many, traditionally separate, conventional approximations are derived from within this one approach. Furthermore, I show that beam theories are convergent, at least for the circular rod, and obtain an accurate estimate of the limit of their validity. The approximate evolution equations derived by this invariant manifold approach are complete with appropriate initial conditions, forcing and, in at least one case, boundary conditions.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 2401-2413 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The considerable potential of high resolution time-resolved spectroscopic data for copolymer systems in elucidation of the intramolecular photophysical processes which occur in polymer systems is illustrated. Such information can not be gleaned solely from studies of homopolymers. Kinetic data and time resolved fluorescence spectra of copolymers of 1-vinylnaphthalene and methyl methacrylate indicate that conventional kinetic schemes are inappropriate for the discription of excimer formation in 1-vinylnaphthalene polymers. Evidence is presented for the presence of an emitting species in addition to the expected monomeric and excimeric forms. The nature of this third species is discussed and photophysical kinetic schemes are proposed to describe intramolecular excimer formation in such systems. Kinetic data have been derived for the principle deactivation pathways through investigation of the observed fluorescence decays upon the intrachain concentration of aromatic species.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The time-resolved fluorescence behavior of polystyrene and a series of styrene-methyl methacrylate copolymers has been examined by using pulsed laser excitation. Although the photophysical characteristics of styrene- and naphthalene-containing polymers may be described by the same general kinetic scheme, some differences in the nature of the photophysical interactions are apparent. Umambiguous evidence for the occurrence of excimer dissociation into excited-state monomer in polymers incorporating styrene chromophores is presented.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The use of pulsed laser excitation upon a series of 1-vinylnaphthalene/methyl methacrylate co-polymers in which the intramolecular chromophore concentration is varied over a wide composition range has allowed the individual rate constants governing intramolecular excimer formation to be determined at various temperatures between 205 and 295 K. Triple exponential functions are necessary for adequate description of the photophysical kinetics over the entire temperature range. It is proposed that the kinetic and temperature behavior is consistent with a kinetic scheme involving two kinetically distinct monomeric species and an excimer in which energy may be transferred from the second monomer M*2 to the first monomer M*1 which can interact with the excimer by a conventional migration mechanism.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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