ISSN:
1573-9171
Keywords:
2-amino-4-imino-2-perfluoropentene
;
β-aminovinylimine
;
ethylenediamine
;
diethylenetriamine
;
transamination
;
N-heterocycles
;
intramolecular nucleophilic substitution
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The transamination of 2-amino-4-imino-2-perfluoropentene with ethylenediamine gives the corresponding 6-fluoro-5,7-bis(trifluoromethyl)-2,3-dihydro-1H-1,4-diazepine. The transamination of 2-amino-4-imino-2-perfluoropentene by diethylenetriamine is accompanied by intramolecular nucleophilic substitution of the α-fluorine atom to form 1,9-bis(trifluoromethyl)-3,4,6,7-tetrahydro-2H-pyrazino[1,2-a]pyrazine whose structure was established by an X-ray structural investigation. Several salts of this bicyclic compound and its complex with BF3 have been described.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00697043
Permalink