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  • Liquid chromatography  (2)
  • 2-p-toluidinyl-6-naphthalenesulfonate  (1)
  • Cation-exchange-induced stationary phases  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 22 (1999), S. 609-612 
    ISSN: 0935-6304
    Keywords: Cyclodextrins ; 2-p-toluidinyl-6-naphthalenesulfonate ; indirect fluorimetric detection ; liquid chromatography ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Cyclodextrins (CD's) were visualized by postcolumn mixing with 2-p-toluidinylnaphthalene sulfonate (TNS) in liquid chromatography. The indirect detection is based on fluorescence enhancement due to the formation of an inclusion complex between TNS and CD's. β-CD gave larger signal intensity than α- and γ-CD. Different selectivities were observed for alkyl-bonded silica stationary phases with different chain length.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 16 (1993), S. 419-421 
    ISSN: 0935-6304
    Keywords: Liquid chromatography ; Indirect conductimetric detection ; Cyclodextrin ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Indirect conductimetric detection of cyclodextrins (CDs) was investigated in liquid chromatography (LC). The mobile phase contained an electrolytic substance which maintained high background, and CDs were indirectly detected owing to a depression of the background signal due to dilution of the mobile phase by the analyte molecules. The dynamic reserve, defined as the ratio of the background to its noise level, was (1-2) × 105, and the detection limits at S/N = 3 were 23-40 ng for CDs when a microcolumn LC system was employed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0935-6304
    Keywords: Liquid chromatography ; Cation-exchange-induced stationary phases ; Retention behavior ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The retention behavior of aromatic hydrocarbons and dansylamino acids on cation-exchangers modified with alkylammonium ions has been examined by microcolumn liquid chromatography. Several parameters affected the retention of analytes, involving concentration of the modifier in the mobile phase, its alkyl chain length and mobile phase composition. Stationary phases modified with a reagent having longer alkyl chains achieved better column efficiency.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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