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  • 1
    Electronic Resource
    Electronic Resource
    Isotope shifts of neutron-deficient gold isotopes with 193≧A≧190 (1985)
    Springer
    The European physical journal 321 (1985), S. 537-547 
    Details
    ISSN: 1434-601X
    Keywords: 21.10.-k ; 27.80+w ; 31.30.Gs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The isotope shift between197Au (stable) and the radioactive Au isotopes190Au,191Au,192Au and193Au were determined by resonance fluorescence spectroscopy in the 6s 2 S 1/2–6p 2 P 1/2.λ=267.6nm line. The unstable Au isotopes were produced at the ISOLDE mass separator at CERN. The nuclei were investigated semi on-line in a resonance vessel, heated to 1,400°C. The results areδν 190,197=−11.12(39) GHz,δν 191,197=−9.67(12) GHz,δν 192,197=−8.32(15) GHz,δν 193,197=−6.29(11) GHz, corresponding to a change of the mean-square charge radius byδ〈r 2〉190,197 =0.261(12) fm2,δ〈r 2〉191,197=0.227(5) fm2,δ〈r 2〉192,197=0.195(5) fm2,δ〈r 2〉193,197 =0.148(4) fm2.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01432427
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Small-angle X-ray scattering studies of Nafion®/[silicon oxide] and Nafion®/ORMOSIL nanocomposites (1996)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 1917-1923 
    Details
    ISSN: 0887-6266
    Keywords: SAXS ; Nafion® ; ORMOSIL ; sol-gel reaction ; nanocomposite ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The small angle X-ray scattering technique was used to probe structural heterogeneity on the scale of nanometers within Nafion®/[silicon oxide], Nafion®/[ORMOSIL], and Nafion®/[dimethylsiloxane] hybrid membranes. The results of this study reinforced the working hypothesis of morphological template action for the in situ growth of silicon oxide, or organically modified silicon oxide phases in perfluorosulfonate ionomers via sol-gel reactions for silicon alkoxide or/and silicon alkylalkoxide precursors. Nanophase separation persists when incorporated silicon oxide particles are postreacted with ethoxytrimethylsilane but postreaction with diethoxydimethylsilane generates co-continuous phases that do not generate ionomer SAXS peaks, presumably due to a more homogeneous Si atom distribution within the ionomer. These hybrids are true nanocomposites, as structural heterogeneity exists on the scale of ∼ 5 nm. The variation of the small angle upturn for these hybrids is explained in terms of long-range inhomogeneities in ionomers. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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