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  • 25.70. Gh  (1)
  • compensation temperature  (1)
  • fictive temperature  (1)
  • 1
    Electronic Resource
    Electronic Resource
    The glass transition (1996)
    Springer
    Journal of thermal analysis and calorimetry 47 (1996), S. 887-896 
    Details
    ISSN: 1572-8943
    Keywords: compensation temperature ; DSC ; fictive temperature ; poly(ethylene terephthalate) ; thermally stimulated depolarization current
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract This work deals with a comparison of data obtained from differential scanning calorimetry (DSC) and thermally stimulated depolarization current (TSDC) investigations. Measurements were performed on various poly(ethylene terephthalate) films: a wholly amorphous, a thermally crystallized and drawn samples. For each specimen, the TSDC complex spectra, resolved into elementary ones, led to the determination of the classical compensation temperature (T c ). The glass transition temperature (T g) and the fictive equilibrium temperature (T f) were determined by means of DSC. It appears thatT c is different fromT g and very close toT f.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01981823
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  • 2
    Electronic Resource
    Electronic Resource
    Competition between few nucleon emission andγ-ray deexcitation for the reaction systems65Cu+87Rb and40Ar+110Pd (1985)
    Springer
    The European physical journal 322 (1985), S. 393-414 
    Details
    ISSN: 1434-601X
    Keywords: 24.60. Dr ; 25.70. Gh ; 25.70. Jj
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Bothγ-ray and neutron emission have been studied for the reaction systems65Cu(237MeV) +87Rb→152Dy* and40Ar(158MeV)+110Pd→150Gd*. By using a sum spectrometer in coincidence with neutron counters, Ge(Li) or Nal detectors, we have measured the totalγ-ray energy and the average totalγ-multiplicity distributions as well as the neutron spectra for various exit channels. These measurements provide strong evidence for thermal equilibrium in reactions involving a small number of emitted neutrons (i.e.87Rb(65Cu,n or 2n)) at rather high excitation energy (∼54MeV). This statistical emission of only a few neutrons is controlled by very strong y-ray competition: theγ-entry line is found not to be parallel to the yrast line. Instead the energy gap is about 8MeV for J∼27ħ and rises to at least 13MeV for J∼36ħ. There are some indications that the main part of the energy from this gap is removed by statisticalγ-ray cascades. The main features of the experimental data for both entrance channels are well reproduced by statistical model calculations with proper attention to the yrast line position and an adjustement of the dipoleγ-ray normalization coefficient. It is conceivable that the y-ray enhancement that we introduce may be related to a lack of knowledge of the absolute level densities at high energy and spin, or possibly to the presence of new or additional degrees of freedom that may enter into the competition between neutron andγ-ray emission.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01412074
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    Paper (German National Licenses)
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