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  • 34.80.Gs  (2)
  • 32.30.Bv  (1)
  • 33.40.Hp  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 3 (1986), S. 319-322 
    ISSN: 1434-6079
    Keywords: 36.40.+d ; 34.80.Gs ; 35.20.Wg
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Multiply charged ammonia cluster ions are produced by adiabatic nozzle expansion and subsequent ionization by electron impact. They are analyzed in a double focussing sector field mass spectrometer (reversed geometry). Doubly charged clusters are only detected above a critical size of 51 and triply charged clusters above 121. Some of these multiply charged ions decay via metastable dissociation processes in the experimental time window accessible. Doubly charged ammonia clusters with sizes ofn≧51 lose one neutral monomer or, roughly ten times less probable, two neutral monomers. Conversely, triply charged ammonia clusters with sizes 110≦n≦120 show an extremely asymmetric Coulomb dissociation resulting in doubly charged cluster ions of about 90% of the initial mass
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-6079
    Keywords: 34.80.Gs ; 35.20.Wg
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Electron impact ionization of propane (C3H8) was studied using the ion beam deflection technique and a double focussing mass spectrometer in conjunction with a recently developed correction procedure that accounts for discrimination due to the initial kinetic energy of fragment ions. The relative corrected partial ionization cross sections for the production of C3H 8 + , C3H 7 + , C3H 6 + , C3H 5 + , C3H 4 + , C3H 3 + , C3H 2 + , C3H+, C 3 + ; C2H 5 + , C2H 4 + , C2H 3 + , C2H 2 + , C2H+, C 2 + ; CH 3 + , CH 2 + , CH+, C+; C3H 5 2+ , C3H 4 2+ , C3H 3 2+ and C3H 2 2+ were determined from threshold up to 950 eV. Absolute partial ionization cross sections were obtained by charge weighted summing of all the observed partial ionization cross sections and by normalizing to a recent accurate determination of the total ionization cross section at 100 eV by Djuric et al. 1991. The absolute total ionization cross section curve obtained is in excellent agreement in shape and magnitude with the low energy data (〈200 eV) of Djuric et al. 1991 and the high energy data points of Schram et al. 1966.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-6079
    Keywords: 36.40 ; 33.40.Hp ; 32.30.Bv
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new metastable decay reaction of ArnO+ cluster ions produced by the electron impact ionization of argonoxygen clusters has been discovered, leading to the evaporation of more than two monomers in the metastable time regime. It is estimated that an energy of approx. 1 eV has to be released from the intramolecular to intermolecular modes prior to this metastable decay. In contrast to previously observed excimer-induced fragmentation of pure argon cluster ions, it has been concluded that the localized metastable state of an ionic rather than a neutral species is involved in the fragmentation. A reaction mechanism involving an electronic transition from the a2Π ArO+* (O(3P)-Ar+(2P)) excited state to the X4Σ− ArO+ (O+(4S)-Ar(1S)) ground state of the ArO+ complex ion within the cluster and subsequent release of considerable amount of vibrational energy to cluster modes is suggested to account for the observed fragmentation. Based on these measurements, a lifetime of approx. 2 µsis proposed for the excited state a2Π ArO+*.
    Type of Medium: Electronic Resource
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