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The relationship of Au55(PPh3)12Cl6 to colloidal gold (1989)

Benfield, R. E. ; Creighton, J. A. ; Eadon, D. G. ; [et al.]

Springer

The European physical journal 12 (1989), S. 533-536

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ISSN: 1434-6079

Keywords: 33.20.K ; 35.20.G ; 36.40

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The electronic (UV-visible) spectrum of the molecular cluster Au55(PPh3)12Cl6 shows features corresponding to the 520 nm plasma resonance and the shorter-wavelength interband transition of colloidal gold. These absorptions differ qualitatively from the simpler one-electron transitions of lower-nuclearity cluster molecules. Differential scanning calorimetry has been used to measure the enthalpy of decomposition of Au55(PPh3)12Cl6. The Au-Au bonding appears to be substantially stronger than in bulk gold.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01427012

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