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Ion-dip Raman spectroscopy: A method to measure Raman spectra at 4×10−9 bar (1984)

Bronner, W. ; Oesterlin, P. ; Schellhorn, M.

Springer

Applied physics 34 (1984), S. 11-15

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ISSN: 1432-0649

Keywords: 33.80 Kn ; 42.65 Cq

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract It is demonstrated that a combination of resonant multiphoton ionization and stimulated Raman scattering, known as the “ion-dip” method, can generate Raman signals at very low densities. Using thev 1 mode of benzene at 3075 cm−1, we show that even with moderate laser power, Raman spectroscopy with nonresonant excitation can be performed at densities of 1011 mol/cm3 or 4×10−9 bar, several orders of magnitude lower than with any other type of Raman scattering. The possibility of Raman spectroscopy of atomic and molecular clusters is discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00697458

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