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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied mathematics & optimization 27 (1993), S. 1-33 
    ISSN: 1432-0606
    Keywords: Hamilton-Jacobi equations ; Viscosity solutions ; Extinctiontime property ; Representation formulae ; Primary 49C10 ; 35L60 ; Secondary 35D05 ; 35C99
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract In this paper we study initial value problems likeu t−R¦▽u¦m+λuq=0 in ℝn× ℝ+, u(·,0+)=uo(·) in ℝN, whereR 〉 0, 0 〈q 〈 1,m ≥ 1, andu o is a positive uniformly continuous function verifying −R¦▽u o¦m+λu 0 q ⩾ 0 in ℝ N . We show the existence of the minimum nonnegative continuous viscosity solutionu, as well as the existence of the function t∞(·) defined byu(x, t) 〉 0 if 0〈t〈t ∞(x) andu(x, t)=0 ift ≥t ∞(x). Regularity, extinction rate, and asymptotic behavior of t∞(x) are also studied. Moreover, form=1 we obtain the representation formulau(x, t)=max{([(u o(x − ξt))1−q −λ(1−q)t]+)1/(1−q): ¦ξ¦≤R}, (x, t)εℝ + N+1 .
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-2234
    Keywords: Vibronic intensities ; Vibrational coordinates ; Crystal field ; Ligand polarization ; Complex ion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A reexamination of the vibrational coordinates appropriate in vibronic intensity calculations in octahedral coordination compounds is presented. We derive a complete set of symmetry coordinates that is orthonormal and transforms correctly under the group generators. The vibronic hamiltonian for the crystal field and ligand polarization contributions to the intensity are calculated in the basis of these coordinates. The crystal field term is evaluated both using a truncated basis set for the intermediate electronic states and using the closure approximation. These methods have been applied to the calculation of the vibronic intensity distribution for the4 A 2g ↔2 E g transition of the MnF 6 2− ion and close agreement wtih experiment achieved.
    Type of Medium: Electronic Resource
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