ISSN:
1434-6079
Keywords:
36.40+d
;
82.60
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract Enthalpy, Entropy, and Gibb's free energy changes for the clustering reactions of Na+ and Pb+ with several important atmospheric molecules and organic solvents have been measured by using high pressure mass spectrometry (HPMS). The unusually strong bonding has been found in Na+ ion complexes where ligands have large high moments and polarizabilities as well as in Pb+ ion complexes. The enhancement of the bonding by ion-high moment, ion-induced dipole, and dispersion interactions may account for the strong bonding in some of Na+ ion complex systems, while the strong bonding in Pb+ ion complexes may results from the hybridization of 6s and 6p orbitals of Pb+ ion.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01448337
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