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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 19 (1991), S. 241-245 
    ISSN: 1434-6079
    Keywords: 75.50.Bb ; 36.40. +d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The Stern-Gerlach deflections of small alkali clusters (N〈6) and iron clusters (10〈N〈500) show that the paramagnetic alkali clusters always have a non-deflecting component, while the iron clusters always deflect in the high field direction. Both of these effects appear to be related to spin relaxation however in the case of alkali clusters it is shown that they are in fact caused by avoided level crossing in the Zeeman diagram. For alkali clusters the relatively weak couplings cause reduced magnetic moments where levels cross. For iron clusters however the total spin is strongly coupled to the molecular framework. Consequently this coupling is responsible for avoided level crossings which ultimately cause the total energy of the cluster to decrease with increasing magnetic field so that the iron clusters will deflect in one direction when introduced in an inhomogeneous magnetic field. Experiment and theory are discussed for both cases.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 19 (1991), S. 133-135 
    ISSN: 1434-6079
    Keywords: 36.40. +d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The experimental polarizabilities, ionization potentials and electron affinities of aluminum clusters are compared with jellium predictions. It is found that the clusters have radii and work functions which are close to the jellium model predictions for clusters with more than 13 atoms. The polarizabilities of Al n correspond with the jellium only forn〉40 and the shell structure features in the ionization potentials are anomalous up to 37. We conclude that nonjellium effects are important up ton=40.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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