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  • 36.40.d  (1)
  • PACS. 33.15.Kr Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility - 34.70.+e Charge transfer - 61.48.+c Fullerenes and fullerene-related materials  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Electric dipole moment and charge transfer in alkali-C molecules (2000)
    Springer
    The European physical journal 12 (2000), S. 147-151 
    Details
    ISSN: 1434-6079
    Keywords: PACS. 33.15.Kr Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility - 34.70.+e Charge transfer - 61.48.+c Fullerenes and fullerene-related materials
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: We have measured the electric dipole moment of isolated alkali-C60 molecules (with alkali = Li, Na, K, Rb, and Cs) by molecular beam deflection experiments. The dipole increases from 12.4 D for LiC60 to 21.5 D for CsC60. These results are compared to those deduced from an analytical polarizable-ion model. This comparison shows that there is a strong electron transfer from the alkali atom to the C60 cage, which is almost complete for KC60 and RbC60.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s100530070051
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Optical absorption of LinH clusters (1993)
    Springer
    The European physical journal 26 (1993), S. 290-292 
    Details
    ISSN: 1434-6079
    Keywords: 36.40.d ; 33.80.Rv
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Photoabsorption spectra of free LinH clusters have been recorded for n=2 to 9. Clusters are produced by coexpansion of 10–100 mbars of lithium vapor and 2–4 bars of a 98 % / 2 % mixture of argon with hydrogen. Two photon ionization was used to study the X ← B system of Li2H while beam depletion spectroscopy was used to measure the absorption cross sections of larger clusters. Most observations may be interpreted by the localization of one electron on the hydrogen bonding in agreement with ionization potential measurements.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01429172
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    Paper (German National Licenses)
    Fulltext
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