ISSN:
0044-2313
Keywords:
4,4,6,6,-Tetrachloro-1′
;
5′-dimethyl-6′-phenoxy-6′-thioxo-cyclotriphosphazene-2-spiro-3-cyclodi-[phosphadiazane]
;
4,4,6,6,8,8-hexachloro-6′-phenoxy-6′-thioxo-cyclotetraphosphazene-2-spiro-3′-cyclodi[phosphadiazane]
;
spiro-phosphazanes; phosphorus-hydrazine heterocycles
;
31P-NMR spectra
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
New Spiro Compounds from Cyclophosphazenes and Cyclodi[phosphadiazanes]Chlorocyclophosphazenes (Cl2P = N)3 and (Cl2p = N)4 react with dihydrazidophosphoric acid derivatives in THF in the presence of triethylamine to give the spirocyclic compounds Cl4N3P3(NHN(CH3))2P(S)OC6H5, Cl6N4P4(NHNH)2P(S)OC6H5. Constitutions have been confirmed by MS, NMR, IR and elemental analysis.
Notes:
Chlorocyclophosphazene (Cl2P=N)3 und (Cl2p = N)4 reagieren mit Dihydraazidophosphorsäure-derivaten in THF in Gegenwart von Triethylamin zu den Spiroverbindungen Cl4N3P3(NHN(CH3))2P(S)OC6H5, Ci6N4P4(NHNH)2P(s) OC6H5. Die Konstitutionen der neuen Verbindungen wurden durch IR-, NMR- und Massenspektren sowie durch Elementaranalysen belegt.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19926090313
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