ISSN:
0749-1581
Keywords:
NMR
;
13C NMR
;
55Mn NMR
;
1J(55Mn, 13C)
;
Organomanganese complexes
;
Lineshape analysis
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
55Mn, 13C coupling constants of σ- and π-organomanganese pentacarbonyl, tetracarbonylphosphine and tricarbonyl complexes were determined by lineshape analysis of the 13CO and 13C(R) signals (R = alkyl, acyl or aryl) using the iterative lineshape fitting program QUADR. The 1J(55Mn, 13C) data are in the range 29-47 Hz for Mn—CO bonds and 2-28 Hz for Mn—R bonds. The 55Mn chemical shifts and linewidths are also reported.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260320607
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