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  • laser irradiation  (2)
  • metabolism  (2)
  • radical addition  (2)
  • 61.72.Ji  (1)
  • 1
    ISSN: 1432-0630
    Keywords: 61.72.Cc ; 61.72.Ji ; 73.61.Cw
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Vacancy-related defects introduced into n-Si during annealing or aluminium diffusion at high temperature (1000–1250°C) have been studied. Different ambients (argon, nitrogen, vacuum and chlorine-containing atmosphere) were used to create a vacancy supersaturation during heat treatments. Three deep-level centers whose formation is governed by the presence of vacancies have been identified. They were characterized by the following temperature dependences of the thermal emission rate:e3 = 7.92 × 107 T 2 × exp(− 0.455/kT),e 5 = 2.64 × 106 T 2 × exp( − 0.266/kT),e 7 = 7.26 × 106 T 2 × exp (− 0.192/kT). The influence of different factors, such as heat-treatment conditions, concentration of oxygen and doping level in initial crystals, on center formation was studied. An asymmetric diffuseγ-ray scattering was observed near the surface of a crystal irradiated by thermal neutrons and annealed in a chlorine-containing atmosphere. This scattering is related to the formation of structural defects of the vacancy type. In the same region of the crystal, the concentration of the E7 center was one order of magnitude higher than that of other deep-level centers. Comparison of theγ-ray diffraction and deeplevel transient spectroscopy (DLTS) data suggests that the formation of the center occurs under the conditions of Si supersaturation with vacancies.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 41 (1992), S. 1750-1755 
    ISSN: 1573-9171
    Keywords: vinyl monomers ; radical addition ; reactivity ; correlation schemes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The concept of the apparent electronegativity of a reaction site has been introduced. This has been used to develop a new scheme for calculating the relative rate constants of addition of radicals with different structures to vinyl monomers. The parameters of the scheme are given for 40 reagents. The results of a comparison of calculated and literature rate constants of addition are presented.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 42 (1993), S. 640-644 
    ISSN: 1573-9171
    Keywords: vinyl monomers ; radical addition ; MO calculations ; transition states of reaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The transition states for the addition of.CH3, CH3O.,.CCl3,.CF3, and HOO. radicals to the Cβ and Cα atoms of ethylene, propylene, styrerie, acrylonitrile, methyl acrylate, vinyl acetate, and vinyl- and vinylidene chlorides were calculated using the MNDO method. A satisfactory correlation between the heats of reaction and activation energies was found. The calculated coefficients of proportionality, 0.4–0.5, are twice as high as those in the Polyani—Semenov equation. The calculated heat of reaction of radical addition was shown to be as «strong» an index of reactivity as the calculated activation barrier.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-8221
    Keywords: myocardial ischemia ; cardiac arrhythmias ; opioid receptors ; laser irradiation ; sympathetic regulation of the heart
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract The effects of intravenous administration of different opioid peptides on the development of ischemic cardiac arrhythmias under conditions of intraatrial laser irradiation (λ=632.8 nm) were studied in cats with transected cardiac branches of the right stellate ganglion and preserved sympathetic innervation of the ischemized area. Ischemia was caused by occlusion of the circumflex branch of the left coronary artery. It was found that the protective effects of dalargin were most powerful when sympathetic influences on the ischemic area were intestified by laser irradiation. Under these conditions DAGO showed more pronounced antiarrhythmic effects than DSLET.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of experimental biology and medicine 126 (1998), S. 1106-1109 
    ISSN: 1573-8221
    Keywords: myocardial ischemia ; cardiac arrhythmias ; ventricular fibrillation ; laser irradiation ; sympathetic cardiac regulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract The role of sympathetic nervous system in the antiarrhythmic effect of intra-atrial laser irradiation (λ=632.8 nm) during myocardial ischemia was studied in acute experiments on Nembutal-anesthetized cats. Laser irradiation applied after bilateral, dextral, or sinistral transection of cardiac branches of stellate ganglia increased the number of ischemic rhythm disturbances that developed after occlusion of the circumflex branch of the left coronary artery. The maximum increase in the number of arrhythmias was observed after dextral transection, the occurrence of ventricular fibrillation being 100%. Bilateral transection provoked a larger number of ischemic rhythm disturbances than the sinistral transection. It is probable that the development of the antiarrhythmic effect of laser irradiation requires sustained sympathetic activity targeted at the nonischemic regions in the myocardium that could play a stabilizing role during local ischemic damage to the heart.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1573-8221
    Keywords: hydra head growth activator ; tissue and organ distribution ; pharmacokinetics ; metabolism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract The organ distribution of radioactivity following intravascular bolus injection of3H-Lys-head growth activator in rats was studied. Two minutes after injection the renal level of radioactivity exceeded the blood level 7-fold; 80% of the total activity was bound with the blood cell membranes. An analysis of chemical derivatives of the labeled peptide in the plasma by means of reverse-phase high-performance liquid chromatography revealed the presence of several groups of radioactive metabolites with different hydrophilic properties. High-performance liquid chromatography of blood extracts obtained from samples taken 0.5, 1, 1.5, 2, 31, and 60 min after injection showed the transformation of initially hydrophobic head growth activator into more hydrophilic fragments. The3H-Lys-head growth activator-associated radioactivity could be reliably detected in the blood onl during the first two minutes after injection. The half-period of blood-to-organ distribution of3H-labeled head growth activator lasted less than 30 seconds.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of experimental biology and medicine 106 (1988), S. 968-970 
    ISSN: 1573-8221
    Keywords: dalargin ; opioids ; metabolism ; bioavailability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Type of Medium: Electronic Resource
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