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  • 1
    ISSN: 1434-6036
    Keywords: 63.50.+x ; 71.20.Ad ; 61.42+h
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present an exact renormalization-group approach to study the local phonon properties of the double-atom generalized Fibonacci systems in which the masses and spring constants are all associated with the aperiodic sequences constructed by the inflation rule: {A, B}→{A n Bm, A}.n(m+1) basic transformations and 2n(n+m−1)+1 basic decimations are introduced. By applying the combinations of derived transformations and decimations, we can determine exactly the renormalized local environment, up to infinite order, of any given site in the double-atom systems. Both the single-atom and double-atom phonon models are employed, and the local density of states in several sites of some generalized Fibonacci systems are numerically calculated.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Cyclodextrin additives ; Fluorescence agents
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary We report four new derivatization agents, acridone-N-acetic acid (ARC), carbazole-9-ylacetic acid (CRA), carbazole-9-ylpropionic acid (CRP), and 2-methyl-2-carbazole-9-ylacetic acid (MCRA), with strong fluorescence emission which has low dependence on solvent polarity. The emission maxima for ARC, CRA, CRP, and MCRA were 430 nm (λex 404 nm), 368 nm (λex 335 nm), 356 nm (λex 340 nm) and 360 nm (λex 330 nm), respectively. The effects of mobile-phase composition, pH, and temperature on the liquid chromatographic retention behavior of the four fluorescence agents were investigated. An experimental model was established for calculating the inclusion constants of cyclodextrin (CD) complexes in the dynamic state, using β-cyclodextrin (β-CD) and hydroxypropyl-β-cyclodextrin (HP-β-CD) as examples, and different mobilephase compositions. On the basis of the model, the inclusion constants of the solutes in pure water (K fw) were determined by extrapolation. The thermodynamic parameters (ΔH o and ΔS o) and dissociation constantsK am for the solutes in this chromatographic system were obtained by means of capacity factor (k) values using a corresponding model formulation.
    Type of Medium: Electronic Resource
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