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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 94 (1990), S. 8356-8359 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 6151-6161 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We provide a comprehensive analysis of the microstructure of the porous glass, vycor. Using transmission electron microscopy, small-angle x-ray scattering, molecular adsorption, and the dynamic process of direct energy transfer, a consistent picture of the mass, pore, and interfacial features of this material is presented. From a transmission-electron-microscopy image of an ultrathin section of vycor the material appears to have a homogeneous distribution of mass with no hierarchical organization. The pore interface exhibits a roughness which is probed by both small-angle x-ray scattering and molecular adsorption. The roughness has an upper cutoff of 〈20 A(ring) which is not resolved in the transmission-electron-microscopy image and is shown to be unimportant to the dynamics of the direct energy transfer process. The dimensionality probed by direct energy transfer is shown to be related to interfacial geometrical crossover from two dimensional to three dimensional, which is characterized by a persistent length of the interface of 45 A(ring).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 4619-4621 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present expressions for the resonant magnetic x-ray scattering from rough surfaces; using our formulas we analyze the structural and magnetic roughnesses, as well as the correlation between them. We demonstrate that the leading contribution to the difference in the diffuse scattering between left- and right-circularly polarized light for a rough surface with in-plane magnetization vanishes unless the structural and magnetic roughnesses are correlated. The effects of magnetic domain structure and magnetic dead layers on the surface scattering are also discussed. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 8536-8542 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report measurements and calculations of x-ray diffuse scattering from the liquid–vapor interface of toluene and polybromostyrene(PBrS)/toluene solutions for polymer molecular weights 90 K and 1 M at concentrations up to 11.7 volume %, well into the entangled semidilute regime. We have calculated the static structure factor S(k) and equal time height–height correlation function C(R) for surface hydrodynamic modes based on a coupled two-fluid model where the polymer response is taken to be that of a Maxwell viscoelastic material [Harden et al., J. Chem. Phys. 94, 5208 (1991)]. We obtain the leading correction term to the capillary-wave result for C(R) dependent on the solution shear modulus E0, as well as an analytic approximation valid for large E0, including the case of pure polymer melt.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 7505-7515 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Real surfaces are rough and chemically heterogeneous on many length scales and wetting phenomena on these surfaces are affected by this inhomogeneous nature. We have used x-ray reflectivity to examine the structure of static precursing films which precede the macroscopic meniscus of water on glass. We have examined the thickness of the film, the roughness of the interfaces bounding the film, and the conformality or correlations between the roughness features of these bounding interfaces. The wetting film consists of three basic components: the bulk meniscus, a thin (≤100 A(ring)) precursing wetting film which has a sudden termination, and beyond that, a much thinner film characteristic of the glass surface in contact with water vapor only. The roughness and chemical heterogeneity of the solid manifest themselves in the roughness of the water/vapor interface of the film, in the irregularity of the terminating boundary of the precursor wetting film, and in the hysteretic pinning of that boundary. The roughness of the glass surface is observed to impose additional roughness to the water/vapor interface beyond that which would exist on a bulk interface. These results are discussed in terms of the disjoining pressure which governs the behavior of such films.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Plasmas 3 (1996), S. 59-63 
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An analysis of second harmonic power generation in collisionless, unmagnetized plasma bounded by parallel plates is presented, which predicts much higher yield under appropriate plate separation and input energy than the maximum reported yield for unbound plasma. One can therefore look for optimization of second harmonic power by choosing suitable parameters. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 5857-5859 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Neutron diffraction has been used to investigate the magnetic order of RNi2B2C. For R=Er the system orders antiferromagnetically at TN=6.8 K, and this long range order coexists with superconductivity (Tc=11 K). The magnetic structure is an incommensurate, transversely polarized spin-density-wave state, with the modulation wave vector δ along the a axis and the moments along b. δ has a temperature-independent value of 0.5526 (2π/a), with the structure squaring up at low temperatures. For R=Ho the moments also prefer to reside in the a–b plane, but initially an incommensurate c-axis spiral state forms upon cooling, with TN≈TC≈8 K. This c-axis spiral consists of ferromagnetic sheets of holmium moments in the a–b plane, but with each sheet rotated by ∼163° as one proceeds along the c axis. Small a-axis peaks are also observed above the reentrant superconducting transition over a narrow temperature range, but the c-axis peaks dominate. Just below the reentrant transition at ∼5 K the magnetic system locks-in to a simple commensurate antiferromagnetic structure, which permits superconductivity to be restored. The c-axis spiral, the a-axis component, the commensurate antiferromagnetic structure, and the superconducting phase are all in a delicate balance energetically, and this balance may be easily shifted by subtle changes in composition, magnetic field, and pressure. DyNi2B2C orders antiferromagnetically at TN=11 K, with the same commensurate antiferromagnetic structure as found for the holmium material at low temperature. The existence of superconductivity in some samples of DyNi2B2C is consistent with the antiferromagnetic structure observed. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 68 (1996), S. 191-193 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: X-ray diffraction measurements in the region of small incidence and exit angles on thin amorphous silicon/germanium films on laterally structured surfaces are performed. From fits of the data we obtain directly how the Fourier components of the substrates propagate through the evaporated films without being influenced by the intrinsic statistical roughness of the interfaces. The results show that a replication factor extracted from a given model can be quantitatively tested with our measurements. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 4214-4214 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We consider the Anderson lattice for finite U using a novel equation of motion technique. The method employs a truncation scheme based on a projection operator which projects out of any operator its exact thermal average in the space of correlated single-particlelike excitations, i.e., excitations both in the presence and absence of the opposite spin state. Thus, this method is good for all U. This is important in these superconducting transition metal oxide systems since experimental evidence has shown that the bandwidth/U is not small. For the single-particle spectrum we naturally generate the anomalous correction induced pairing and resulting gap equation for finite U, in contrast to previous treatments based on the large-U limit, where on-site double occupancy is excluded. The magnetic and pairing susceptibilities are calculated in a similar manner, again for finite U, and the competition between these instabilities will be discussed.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 4015-4018 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic susceptibility measurements on La2CuO4−y have revealed maxima in temperature indicative of antiferromagnetic ordering. Powder diffraction measurements have demonstrated the existence of superlattice peaks at temperatures below those corresponding to the susceptibility maxima, and polarized neutron measurements have confirmed that the peaks are indeed of magnetic origin. The deduced antiferromagnetic structure in the orthorhombic (Cmca) phase of La2CuO4−y consists of ferromagnetic sheets of Cu atoms in the b-c plane which are alternating in sign along the a axis [100]. The moment is parallel to the c axis. The Neel temperature is extremely sensitive to the oxygen deficiency y and decreases rapidly to zero as y goes from 0.03 to 0. The saturated moment is (approximately-equal-to)0.4 μB/Cu atom for samples with the highest TN (290 K). Antiferromagnetic spin fluctuations have also been observed by polarized neutron scattering in the paramagnetic phase above TN. Recent results obtained on magnetic ordering in the YBa2Cu3O6−y family of compounds are also discussed, together with the possible implications for novel superconductivity mechanisms.
    Type of Medium: Electronic Resource
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