ISSN:
1434-6079
Keywords:
82.30
;
79.20.F
;
79.60
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The size of palladium aggregates is monitored with atomic beam technique condensed onto an SiO2 amorphous substrate, by this way it is possible to define an average size that make explicit the intrinsic electronic size effect on a given reaction. The 1,3 hydrogenation of butadiene is followed and it is shown that intrinsic electronic properties observed by A.E.S. and U.P.S. spectroscopies can explain the variation of the turn over frequency.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01427024
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