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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 14 (1977), S. 141-147 
    ISSN: 1432-0630
    Keywords: 82.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We have determined by direct molecular beam velocity measurements that translational energy accommodation of O2 molecules scattered from a hot polycrystalline tungsten target is inefficient at high surface temperatures. Translational energy accommodation is inefficient whether the surface is clean or covered with oxygen to a varying extent, even though in the latter case the scattering is diffuse. On a clean tungsten surface the scattering of the O2 was approximately specular and the reaction probability of O2 was constant and greater than 90% over the temperature range 1000K to 2800 K. It was shown by simultaneous helium scattering that atomic surface roughness of an oxygen chemilayer, rather than trapping, is a major cause of the observed diffuse scattering of oxygen. At the lowest surface temperature of 1000 K, with an oxygen chemilayer present, the velocity of the most probable number density of the scattered O2 was lower than in the incoming beam or than that expected for complete equilibration with the surface.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 14 (1977), S. 411-413 
    ISSN: 1432-0630
    Keywords: 82.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A direct first step in the mechanism for the initial oxidation of a polycrystalline tungsten surface, the catalyzed dissociation of O2 on it, or the formation of WO X by O2 at intermediate temperatures is shown to occur in ∼10−13 s. Molecular beam experiments demonstrated that the reactivity was greater than 90%, the unreacted O2 was substantially unaccommodated in translational energy to the surface temperature, and the reaction probability was nearly independent of surface temperature from 2800 to 415 K although there was a small increase at 415 K. The general conditions when no molecular surface precursor state contributes to the surface reactivity are discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 22 (1990), S. 723-742 
    ISSN: 1573-8868
    Keywords: constrained Delaunay triangulation ; interpolation ; approximation ; B-form representations associated with irregular triangles ; simplex splines
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract In the practice of administrative or engineering geosciences, the problem of deriving a digital surface representation from a map displaying contour lines of the interesting quantity is quite often encountered. First, alpha-numerical data are retrieved from the map by digitizing these contour lines pointwise into polygons. However, common “gridding” algorithms are known to fail at adequately reproducing the input contour lines due to the inhomogeneous and anisotropic areal distribution of the sites of the data sampled from given contour lines. Therefore, we suggest a new algorithm; the basic elements of its first stage are a constrained Delaunay triangulation of the data sites honoring their natural neighborhood relationship—i.e., whether they belong to the same contour line or not, and linear interpolation according to this triangulation of the data domain. In a second stage, a Bezier-Bernstein or simplex B-spline representation is easily achieved if a C1 or C2 smooth representation is required. At this stage, also, discontinuities of the function or its first directional derivatives with known locations in the data domain may be represented, provided this additional information has been taken into account when the triangulation was performed. The algorithm is numerically stable and efficient, and allows external interaction by the user to introduce his/her additional knowledge of the phenomenon to be studied, which may not be explicitly inherent in the available data.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 22 (1990), S. 957-987 
    ISSN: 1573-8868
    Keywords: scattered data ; approximation ; simplicial B-splines ; constrained triangulation ; interactive geometric modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Bivariate quadratic simplicial B-splines are employed to obtain aC 1-smooth surface from scattered positional or directional geological data given over a two-dimensional domain. Vertices are generated according to the areal distribution of data sites, and polylines are defined along real geological features. The vertices and the polylines provide a constrained Delaunay triangulation of the domain. Note that the vertices do not generally coincide with the data sites. Six linearly independent simplex B-splines are associated with each triangle. Their defining knots and finite supports are automatically deduced from the vertices. Specific knot configurations result in discontinuities of the surface or its directional derivatives. Coefficients of a simplex spline representation are visualized as geometric points controlling the shape of the surface. This approach calls for geologic modeling and interaction of the geologist up front to define vertices and polylines, and to move control points initially given by an algorithm. Thus, simplex splines associated with irregular triangles seem to be well-suited to approximate and allow further geometrically modeling of geologic surfaces, including discontinuities, from scattered data. Applications to mathematical test as well as to real geological data are given as examples.
    Type of Medium: Electronic Resource
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