ISSN:
1434-6079
Keywords:
0775
;
3640
;
8240 D
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract A high flux of positively and negatively charged metal cluster ions was produced in a sputtering arrangement, energy-analyzed and mass-filtered. The resulting mono-dispersed cluster ion beam was introduced into a quadrupole drift tube, where it interacted with a laser beam or reacted with an introduced gas. All inelastic scattering events were recorded with a subsequent quadrupole mass filter. The results exhibited a high sensitivity of positively and negatively charged silver clusters Ag n ± (n≤16) with respect to photofragmentation. Ion-molecule reactions of nickel clusters with carbon monoxide allowed to synthesize very interesting organometallic and carbonyl compounds, and the maximum number of ligands provided interesting structural indications.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01384804
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