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Conformations and base-catalyzed equilibrations of N-nitroso-decahydroquinolines and N-nitroso-2-methyldecahydroquinolines (1980)

Vierhapper, Friedrich W.

Springer

Monatshefte für Chemie 111 (1980), S. 551-554

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ISSN: 1434-4475

Keywords: A1,3-strain ; 13C-N M R ; Free energy differences

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Zusammenfassung Die Konformationen der sechs Titelverbindungen wurden mittels13C-NMR Spektroskopie bestimmt. Äquilibrierung der 2-Methyl-verbindungen ergab als Hauptprodukte die Derivate der bei katalytischer Hydrierung in geringster Menge entstandenen Amine.

Notes: Abstract Conformations of six title compounds were determined by13C-NMR spectroscopy. Equilibration of the 2-methyl-compounds gives as main products the derivatives of the amines least abundant in the product mixture of the catalytic hydrogenation.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00903252

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