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Liquid-Crystalline D-Glucose Dialkyl Acetals and Dodecyl D-Glucofuranosides (1994)

Tietze, Lutz F. ; Böge, Kai ; Vill, Volkmar

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 127 (1994), S. 1065-1068

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ISSN: 0009-2940

Keywords: Acetals ; Amphiphiles ; Carbohydrates ; Glucosides ; Liquid crystals ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Two new systems of liquid crystalline glucose derivatives 5a-d, 6a, b are prepared, studied and compared with reference compounds. The α- and β-D-dodecyl glucofuranosides 6a, b show smectic A phases. The clearing points of the furanosides are of the same magnitude as those of the pyranosides. The alkyl glucose acetals 5a-d show columnar discotic phases. The clearing points are about 30°C lower than those of the corresponding thioacetals.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19941270615

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