ISSN:
0749-1581
Keywords:
3β, 16β-Dihydroxy-androst-5-en-17-one
;
3β, 17β-Dihydroxy-androst-5-en-16-one
;
13C NMR spectra
;
Acid-catalysed rearrangement
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The acid-catalysed rearrangement of 3β, 16β-dihydroxyandrost-5-en-17-one to 3β, 17β-dihydroxyandrost-5-en-16-one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2-shift of hydride from C-16α to C-17α.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260260702
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