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  • 1
    Electronic Resource
    Electronic Resource
    Synthesis of the perfluoroacetyldiisopropylmethyl radical (1993)
    Springer
    Russian chemical bulletin 42 (1993), S. 207-208 
    Details
    ISSN: 1573-9171
    Keywords: radical ; perfluoroketone ; synthesis ; ESR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A stable trifluoroacetylperfluorodiisopropylmethyl radical has been prepared by interaction of the (α-fluorosulfonyloxytetrafluoroethyl)perfluorodiisopropylmethyl radical with anhydrous CsF. This reaction is the first example of a chemical transformation of a C-centered radical which is not resonance-stabilized with retention of the radical center.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00700014
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Polyfluorinated enol acetates (1994)
    Springer
    Russian chemical bulletin 43 (1994), S. 170-172 
    Details
    ISSN: 1573-9171
    Keywords: polychlorofluoroketones ; reductive dehalogenation ; polyfluorinated enol acetates ; synthesis ; reactivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The synthesis of polyfluorinated enol acetates has been performed by reductive dechlorination of chloropolyfluoroketones with zinc in Ac2O. Under these conditions, hexafluoroacetone is preferably reduced at the carbonyl group.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00699163
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Conjugated Additions in Hydrogen Fluoride (1969)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 8 (1969), S. 349-356 
    Details
    ISSN: 0570-0833
    Keywords: Hydrogen fluoride ; Solvents ; Fluorination ; Fluorine ; Addition ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fluorine and another substituent can be added in a single step to compounds having CC double bonds in anhydrous hydrogen fluoride. It is possible in this way to obtain e.g. α-fluorinated β-halogeno, β-alkyl, β-nitro, and β-amino compounds, and also (in some cases by secondary reactions) fluorinated ethers, alcohols, esters, and carboxylic acids, β-fluoro alcohols can be obtained by conjugated “hypofluorination” in the presence of oxenium ions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196903491
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    Paper (German National Licenses)
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