ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The catalytic activity of sodium 1-dodecanesulfonate, sodium dodecyl sulfate, disodium 2-dodecyl-1, 3-propanediyl disulfate (1) and trisodium 2, 2-bis(sulfonatemethyl)tetradecylsulfate (2) was tested in the two-phase oxidation of p-xylene with cerium ammonium nitrate (CAN). Also various toluene derivatives were oxidized with CAN in the presence of sodium dodecyl sulfate. The observed reaction enhancements are discussed in terms of the micelle-substrate interaction. The catalytic oxidation of some toluene derivatives (3) with a subsequent thermal rearrangement of the oxidation product offers a simple synthetic route to benzaldehydes 4.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19853270614
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