ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The development of ultraviolet radiation technology to cure or photopolymerize acrylic unsaturated monomers, oligomers, and polymers into tight network structures introduces several adhesion problems that can be related to or associated with interfacial polymer-substrate failure. This paper discusses network formation, polymer-interfacial growth association and failure as a function of the following variables: light intensity (effect on sol/gel conversion), photoinitiator (structurereactivity as a function of conversion), polymer shrinkage, and substrate wetting. The results of this study show that all of the above variables interact in a composite fashion to influence the final properties of the ultraviolet cured coatings.
Additional Material:
12 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760170711
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