ISSN:
0009-2940
Keywords:
Ozonolysis
;
Alkylidenecycloalkanes
;
Carbonyl oxides
;
1,2-Dioxolanes
;
1,2,4-Trioxolanes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis of 1,2-Dioxolanes by Ozonolysis of 1,1-Disubstituted Nonactivated OlefinsOzonolyses of the cyclopropyl-substituted olefins 2a, 2b, and 2c do not produce the carbonyl oxides 1a, 1b, and 1c but formaldehyde oxide (1d); 1d can be trapped by the starting olefin and provides the 1,2-dioxolanes 6a, 6b, and 6c, respectively, in ca. 10% yield. Other dioxolanes and normal ozonides may be obtained by the addition of olefins or aldehydes to solutions of the primary ozonides of 2a and 2b.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250131
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