ISSN:
0947-3440
Keywords:
Alkynes
;
Ozonolysis
;
Hydroperoxides
;
Oximes
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Ozonolyses of four symmetrically substituted (13a-13d) and of four unsymmetrically substituted acetylenes (17a-17d) gave all of the expected α-oxo methoxyhydroperoxides (14a-14d, 18ae-18de, 19ae-19de) with good selectivities. The labile, non-isolable hydroperoxides were converted into the corresponding O-methyl oximes (15, 18f, 19f), which could be isolated as stable compounds.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199719970418
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