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  • 1
    Electronic Resource
    Electronic Resource
    Synthesis and Structure of Allenyl-Substituted η6-Benzene(tricarbonyl)-chromium Complexes (1997)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1135-1139 
    Details
    ISSN: 0009-2940
    Keywords: Arene complexes ; Chromium ; Allenes ; Rearrangements ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Cr(CO)3-complexed η6-phenylpropargylic alcohols 3 react in a displacement rearrangement with thionyl chloride or chlorodiphenylphosphane to give the chloro- or phosphoryl allenyl substituted η6-phenyl complexes 4 and 6, respectively. In the X-ray crystal structure of the novel organometallic allenic derivatives 4b and 6b the vicinal chloro or phosphoryl substituent and the benzene(tricarbonyl)chromium fragment are arranged coplanarily. Palladium/copper-catalyzed couplings of the chloroallene 4b with terminal alkynes disclose a facile access to ynallene derivatives 8, novel carbon-rich organometallic π-systems.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19971300816
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Sidechain Functionalizations by Cuprate Additions to Phosphorylallenyl-Substituted Arenetricarbonylchromium Complexes (1999)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 225-233 
    Details
    ISSN: 1434-1948
    Keywords: Arene complexes ; Chromium ; Sidechain functionalization ; Allenes ; Cuprates ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The cuprate addition to (arene)Cr(CO)3-substituted phosphorylallenes 1 gives rise to the regioselective formation of complexed allylphosphane oxide derivatives 3a-c and allylphosphonate derivatives 3d-j in good yields. In the case of racemic planar chiral ortho-substituted complexed (arylallenyl)phosphonates 1c, d the protonation of the intermediate allyl anion proceeds diastereoselectively due to the hindered rotation around the Cipso-Cα bond. This diastereoselective protonation is discussed on the basis of the conformational analysis as deduced from the X-ray structure analyses of the allenylphosphonate 1d and the allylphosphonates 3i, j.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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