ISSN:
0009-2940
Keywords:
1,3,2λ5,4λ5-Dithiadistannetane, 2,4-bis[benzoyl(thiobenzoyl)methanato-O,S]-2,4-dibutyl-
;
Anisobidentate ligands
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Butyltin triisopropoxide reacts with benzoyl(thiobenzoyl)methane (LH) to yield BuSn(S)L and an organic sulfide 2 instead of the expected BuSnL3. The use of other butyltin(IV) starting materials invariably leads to the same products. From an X-ray structure determination the tin sulfido complex is found to be a centrosymmetric dimer, [BuSn(S)L]2 (1) with a planar four-membered Sn2S2 ring containing pentacoordinated tin atoms.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240113
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