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  • Inorganic Chemistry  (4,486)
  • Analytical Chemistry and Spectroscopy  (3,591)
  • Engineering General  (1,137)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 19 (1983), S. 725-737 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: We have assessed the accuracy of a commercially available computer software package for finite element method calculations of magnetostatic fields. The computer program, MSC/NASTRAN,Available from the MacNeal-Schwendler Corporation, Los Angeles, CA 90041, U.S.A. is well known for its wide applicability in structural analysis and heat transfer problems. We exploit the fact that the differential equations of magnetostatics are identical to those for heat transfer if the magnetic field problem is formulated with the reduced scalar potential.1 Consequently, the powerful, optimized numerical routines of NASTRAN can immediately be applied to two- and three-dimensional linear magneto-statics problems. Application of the NASTRAN reduced scalar potential approach to a ‘worst case’ two-dimensional problem for which an analytic solution is available has yielded much better accuracy than was recently reported2 for a reduced scalar potential calculation using a different finite element program. Furthermore, our method exhibits completely satisfactory performance with regard to computational expense and accuracy for a linear electromagnet with an air gap. Our analysis opens the way for large three-dimensional magnetostatics calculations at far greater economy than is possible with the more commonly used vector potential and boundary integral methods.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The establishment of reliable values for concentrations of 16 priority pollutant polycyclic aromatic hydrocarbons (PAH) in a suite of marine sediment reference materials included an examination of the methods used to determine such compounds. Results from the five techniques used indicate large method biases. The biases arise from chemical interferences in methods which use non-selective measuring systems with separation techniques which do not first completely resolve the analytes; e.g., single-parameter optical detectors with high performance liquid chromatographic (HPLC) techniques or a flame ionisation detector (FID) with capillary column gas chromatographic (GC) methods. Measurement by a mass spectrometer with HPLC and GC removes much of the method bias. Results for a representative sediment are discussed to illustrate these conclusions.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A benzenesulphonic acid-type cation exchanger (pKa 〈 1) is used as trapping-column material in a phase-system switching for the on-line coupling of column liquid chromatography and thermospray mass spectrometry. Phase-system switching is used to remove non-volatile constituents from the mobile phase, so that eluents containing non-volatile buffers and ion-pairing agents can be used without contaminating the mass spectrometer. The total analytical system is optimized using four benzalkonium test compounds (quaternary ammonium compounds). The reversed-phase separation of the test compounds as well as the parameters involved in the sorption on and desorption from the trapping column are studied. Important parameters during sorption are the concentration of the phosphate buffer and the percentage of acetonitrile in the mobile phase. During desorption of the test compounds from the ion-exchanger the percentage of acetonitrile in the desorption eluent and the pH are the most important factors. As an example, the analysis of domiphen in nasal drops is shown.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Complexes of the type [crown+M]+ were observed following laser desorption ionization of 18-crown-6 molecules ‘doped’ with K+, Cs+, and Ba+. Laser desorption ionization of 15-crown-5 and 12-crown-4 ‘doped’ with the same metals gave [(crown)]2+[M]+ type sandwich complexes. Binding energies of crown ethers with different metal ions in all such complexes have been estimated from appearance energies obtained in the collisionally-activated dissociation of the corresponding laster desorbed complexes.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 11 (1977), S. 593-597 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Theoretical error bounds of the form are often available for finite element solutions U of elliptic problems. In this form the estimates give the order of convergence of the method but are of little practical value for estimating the size of the error because the magnitudes of the constant K and the theoretical solution u are unknown. An exception occurs in the case of the equation ∂2u/∂x2 + ∂2u/∂y2 + f = 0 in a rectangle where the Ritz-Galerkin finite element solution involves piecewise linears over a regular triangular grid. In this case where α = 1 and Barnhill and Gregory1 have obtained the theoretical value 0·93√2 for K. In this note calculations are carried out for a variety of problems and the quantity K* = ∥u - U∥E/h∥f∥L2 measured and compared with K. The values of K* obtained fit into a well defined pattern from which we conclude that the theoretical constant K is of the correct order of magnitude.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 20 (1984), S. 15-24 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The present paper attempts to evaluate the fracture mechanics parameters, the stress intensity factor (K) and Rice's energy integral (J) in plane strain conditions for three-point bend specimens. Both the parameters have been evaluated by the FEM using higher order isoparametric elements (i.e. quadratic elements). The crack tip elastic singularity (1/√r) has been taken into account by the use of the special crack tip elements of degenerate triangular element type as well as the fine eight-noded isoparametric plane elements. The stress distribution has been compared with the Westergaard solution in the vicinity of the crack. The K and J values have also been-compared with the theoretical results.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 15 (1980), S. 911-923 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A quadratic method is presented for solving the eigenvalue problem of a structural system having a large number of degrees-of-freedom. The eigenproblem is reduced to a smaller problem by condensing the system stiffness and mass using Guyan reduction. Application of a set of corrective displacements to the reduced system subsequently leads to an eigenproblem of quadratic form involving an additional mass term. To obtain the solution to the reduced problem, inverse iteration with spectrum shifts based on the eigenvalues of the Guyan problem is used. The resulting eigenvalues and mode shapes represent a corrected Guyan approximation to the solution of the unreduced system. In addition, it is shown that the amount of improvement over the Guyan solution can be approximated by employing a first-order error analysis procedure. Numerical examples of vibrations of a bar, a beam and a plate demonstrate that the solutions obtained from the quadratic reduction procedure are very accurate and require relatively little additional computational effort in comparison with the solutions of the corresponding linear eigen-problem. The relationship of the present method to that proposed by Przemieniecki is illustrated by an example.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Biomedical Chromatography 9 (1995), S. 226-228 
    ISSN: 0269-3879
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: A steroeselective method, involving a single liquid-liquid extraction step, was developed and validated for the analysis of nadolol in human plasma. The assay involved extraction of nadolol and desmethyl-nadolol as internal standard (IS) from alkalinized plasma into dichloromethane. The organic solvent was separated and evaporated under nitrogen at 40°C. A chiral derivatization scheme with (R)-(-)-napthylethylisocyanate (50 μL of 0.1% solution in dichloromethane for 60 min) was employed to convert the enantiomers of nadolol into the corresponding diastereomeric derivatives. The residue was reconstitutd in the mobile phase and injected onto a C-18 column. The mobile phase was a mixture of methanol: tetrahdrofuran: water (52:7:41 by vol) containing about 0.001% v/v of both phosphoric acid and tetramethylethylenediamine. Fluorimetric detection was performed at excitation 230 and emission 330 nm. The assay was specific for the enantiomers of nadolol and the lower limit of quantitation was 2 ng/mL for of the enantiomers. Analysis of quality control samples resulted in precision estimates of 7% RSD for inter-assay and 10.1% RSD for intra-assay and the predicted concentrations deviated less than 9.4% of the nominal values for the four enantiomers. The extraction recoveries of the individual enantiomer was about 70%. Stability of nadolol enantiomers were established for four freeze/thaw cycle periods and in the autosampler at 5°C for at least 116 h.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 15 (1988), S. 205-209 
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The metabolites of tiropramide were extracted from the urine of healthy volunteers given tiropramide hydrochloride orally. Eight metabolites of tiropramide were found by gas chromatography/mass spectrometry. Three were identified on the basis of their mass spectra, retention times and comparison with synthetic standards. For the others a probable structure is proposed on the basis of their mass spectra.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: By means of laser microprobe mass analysis (LAMMA), we have studied the ultrastructural localization of aluminium in livers of aluminium maltol-treated rabbits. This animal model was developed to study long-term aluminium toxicity using systemic (intravenous) administration of aluminium. We could only detect aluminium in electron-dense inclusion bodies found in large, sometimes multinucleated cells. These results prove that the actual observation of aluminium deposits in liver with LAMMA gives more information than bulk analysis and can be very useful to explore mechanisms of toxicity.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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