ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Carbon-13 NMR data are reported for a series of 1,2-diaryl-4-oxo-4,5,6,7-tetrahydroindoles, 6-methyl-2-phenyl-4-oxo-4,5,6,7-tetrahydrobenzofuran and 1-,6-dithiaindan-4-one. The chemical shifts δ 193-196, δ 195.5 and δ 184 are identified for the carbonyl carbon (C-4) in the tetrahydroindoles, tetrahydrobenzofuran and dithiaindan derivatives, respectively. These shifts are located in the same region as that reported for the corresponding carbonyl carbon in aryl conjugated ketones. An excellent correlation between the chemical shift for the carbonyl carbon and the chemical reactivity of the ketonic function is noticed in the case of the latter two series of ketones while such a correlation is typically absent in the case of the 4-ketotetrahydroindole derivatives.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270110910
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