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Hydrogen rearrangements in alkyl-, styryl- and alkyl propenyl sulfoxides (1989)

Liu, Lilian Kao ; Su, C. Y. ; Li, Wen-Shan

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 24 (1989), S. 338-342

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The McLafferty-type rearrangements, which are the most facile fragmentation for the styryl- and the alkyl propenyl sulfoxides, have been proven to involve at least a β-hydrogen by deuterium labelling studies. γ-Hydrogen also rearranges, yet a cyclopropane instead of an alkene is eliminated. Furthermore, alkyl propenyl sulfoxides undergo hydrogen migration only to the surfinyl oxygen.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210240508

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