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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    European food research and technology 202 (1996), S. 481-485 
    ISSN: 1438-2385
    Keywords: Pomegranate ; Ripening ; Cold storage ; Quality parameters ; Anthocyanin pigments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The changes in the quality parameters of Spanish pomegranate fruit (cultivar Mollar) during ripening and during 7 weeks of cold storage at 5°C and 90–95% relative humidity were studied. The fruit and seed weights, as well as the surface colour increased with ripening. Total soluble solids (TSS), pH and titratable acidity (TA) did not show significant differences during the weeks studied (from the 26th to 32nd weeks after flowering), but the seeds' colour (“Lab” values) and juice colour (absorbance at 510 nm) showed an increase during this period with a maximum during the last 2 weeks. These results indicate that pomegranates should be harvested during the 31st to the 32nd after flowering, in order to get the best pigmentation without a decrease in other quality parameters. The anthocyanin profile changed during the different maturity stages, since the diglucoside derivatives were the prevailing pigments during the early ripening stages, whereas the monoglucoside derivatives were the main pigments in the latter stages. After cold storage of pomegranates harvested at two maturity stages, no differences in TSS, pH, TA and skin colour were observed. In addition, seeds' and juice colour did not decrease during storage. Hence, this study supports the theory that pomegranate is a nonclimacteric fruit and that pomegranates can be stored for at least 45 days without deterioration in the fruit quality.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 31 (1987), S. 903-925 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Even when each atom of a 2n-center cluster or molecule only brings one active electron in one atomic orbital, the size of the Heisenberg Hamiltonian matrix increases as C2nn. Simple truncations of this matrix would result in size consistence defects, as evident from the isomorphism between Heisenberg and configuration interaction (CI) matrices. Geometry-dependent Heisenberg Hamiltonians derived from accurate ab initio calculations on the two-center systems have proved to be very efficient for conjugated hydrocarbons and for alkali metals; in order to apply this approach to intermediate size systems (10-20 centers), a rational procedure is proposed consisting of the selection of a truncated set of determinants (of low energy) and a dressing of the truncated Hamiltonian matrix under the perturbation of the other determinants. The second order dressing is analogous to a so-called “shift Bk procedure” or Generalized Degenerate Perturbation theory and is weakly dependent on an E0 parameter. Tests performed on various 8- and 10-atom systems show the accuracy of the procedure. An iterative selection of the truncated basis set and proper choices of the E0 values allow one to obtain the whole lower part of the spectrum. The calculated geometries are satisfactory. Some preliminary applications are reported concerning the C12H14 dodecahexene linear chain, perfectly fitting with previous extrapolations.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 54 (1995), S. 3-11 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Variational calculations for the lowest-energy states of the hydrogen atom confined in (A) semi-infinite spaces with paraboloidal boundaries, (B) symmetrical boxes with paraboloidal surfaces, and (C) prolate spheroidal boxes were performed with geometry-adapted trial wave functions. Comparisons of variational energies with the exact energies available for the respective geometries provide indications on the reliability of the trial wave functions. This is a necessary and preliminary step to investigate atoms with several electrons in the corresponding confining geometries. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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